Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane

The title compound, C(29)H(37)BrSi, was synthesized by the Sonogashira coupling of [(3,5-diethyl-4-ethynylphen­yl)ethyn­yl]triiso­propyl­silane with 4-bromo-1-iodo­benzene. In the structure, the two phenyl rings are nearly parallel to each other with a dihedral angle of 4.27 (4)°. In the crystal, π–...

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Detalles Bibliográficos
Autores principales: Shu, Caiyun, Moxey, Graeme J., Barlow, Adam, Morshedi, Mahbod
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420139/
https://www.ncbi.nlm.nih.gov/pubmed/25995927
http://dx.doi.org/10.1107/S2056989015007252
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author Shu, Caiyun
Moxey, Graeme J.
Barlow, Adam
Morshedi, Mahbod
author_facet Shu, Caiyun
Moxey, Graeme J.
Barlow, Adam
Morshedi, Mahbod
author_sort Shu, Caiyun
collection PubMed
description The title compound, C(29)H(37)BrSi, was synthesized by the Sonogashira coupling of [(3,5-diethyl-4-ethynylphen­yl)ethyn­yl]triiso­propyl­silane with 4-bromo-1-iodo­benzene. In the structure, the two phenyl rings are nearly parallel to each other with a dihedral angle of 4.27 (4)°. In the crystal, π–π inter­actions between the terminal and central phenyl rings of adjacent mol­ecules link them in the a-axis direction [perpendicular distance = 3.5135 (14); centroid–centroid distance = 3.7393 (11) Å]. In addition, there are weak C—H⋯π inter­actions between the isopropyl H atoms and the phenyl rings of adjacent mol­ecules.
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spelling pubmed-44201392015-05-20 Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane Shu, Caiyun Moxey, Graeme J. Barlow, Adam Morshedi, Mahbod Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(29)H(37)BrSi, was synthesized by the Sonogashira coupling of [(3,5-diethyl-4-ethynylphen­yl)ethyn­yl]triiso­propyl­silane with 4-bromo-1-iodo­benzene. In the structure, the two phenyl rings are nearly parallel to each other with a dihedral angle of 4.27 (4)°. In the crystal, π–π inter­actions between the terminal and central phenyl rings of adjacent mol­ecules link them in the a-axis direction [perpendicular distance = 3.5135 (14); centroid–centroid distance = 3.7393 (11) Å]. In addition, there are weak C—H⋯π inter­actions between the isopropyl H atoms and the phenyl rings of adjacent mol­ecules. International Union of Crystallography 2015-04-18 /pmc/articles/PMC4420139/ /pubmed/25995927 http://dx.doi.org/10.1107/S2056989015007252 Text en © Shu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shu, Caiyun
Moxey, Graeme J.
Barlow, Adam
Morshedi, Mahbod
Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title_full Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title_fullStr Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title_full_unstemmed Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title_short Crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
title_sort crystal structure of ({4-[(4-bromo­phen­yl)ethyn­yl]-3,5-di­ethyl­phen­yl}ethyn­yl)triiso­propyl­silane
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420139/
https://www.ncbi.nlm.nih.gov/pubmed/25995927
http://dx.doi.org/10.1107/S2056989015007252
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AT moxeygraemej crystalstructureof44bromophenylethynyl35diethylphenylethynyltriisopropylsilane
AT barlowadam crystalstructureof44bromophenylethynyl35diethylphenylethynyltriisopropylsilane
AT morshedimahbod crystalstructureof44bromophenylethynyl35diethylphenylethynyltriisopropylsilane

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