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Infrared identification of the Criegee intermediates syn- and anti-CH(3)CHOO, and their distinct conformation-dependent reactivity

The Criegee intermediates are carbonyl oxides that play critical roles in ozonolysis of alkenes in the atmosphere. So far, the mid-infrared spectrum of only the simplest Criegee intermediate CH(2)OO has been reported. Methyl substitution of CH(2)OO produces two conformers of CH(3)CHOO and consequent...

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Detalles Bibliográficos
Autores principales:	Lin, Hui-Yu, Huang, Yu-Hsuan, Wang, Xiaohong, Bowman, Joel M., Nishimura, Yoshifumi, Witek, Henryk A., Lee, Yuan-Pern
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Pub. Group 2015
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4432623/ https://www.ncbi.nlm.nih.gov/pubmed/25959902 http://dx.doi.org/10.1038/ncomms8012

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