Crystal structure of bis­(4-acetyl­pyridine-κN)bis­(ethanol-κO)bis­(thio­cyanato-κN)manganese(II)

In the crystal structure of the title compound, [Mn(NCS)(2)(C(7)H(7)NO)(2)(C(2)H(5)OH)(2)], the Mn(II) atom is coordin­ated by two N-bonded thio­cyanate anions, two 4-acetyl­pyridine ligands, and two ethanol mol­ecules within a slightly distorted octa­hedron. The asymmetric unit consits of one manga...

Descripción completa

Detalles Bibliográficos
Autores principales: Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438791/
https://www.ncbi.nlm.nih.gov/pubmed/26029412
http://dx.doi.org/10.1107/S2056989015004533
Descripción
Sumario:In the crystal structure of the title compound, [Mn(NCS)(2)(C(7)H(7)NO)(2)(C(2)H(5)OH)(2)], the Mn(II) atom is coordin­ated by two N-bonded thio­cyanate anions, two 4-acetyl­pyridine ligands, and two ethanol mol­ecules within a slightly distorted octa­hedron. The asymmetric unit consits of one manganese cation, located on a centre of inversion, one thio­cyanate anion, one 4-acetyl­pyridine ligand and one ethanol mol­ecule in general positions. The discrete complexes are connected by inter­molecular O—H⋯O hydrogen bonds between the alcohol OH group and the carbonyl O atom into chains parallel to [011].

Ejemplares similares