Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)

The mol­ecule of the title compound, [PtH(2)(C(6)H(18)N(3)P)(2)], has a centrosymmetric square-planar structure in which the Pt(II) atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt(II) atom sits on an inversion center and thus the asymmetric unit contains only half t...

Descripción completa

Detalles Bibliográficos
Autores principales: Downs, Emma L., Zakharov, Lev N., Tyler, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438795/
https://www.ncbi.nlm.nih.gov/pubmed/26029413
http://dx.doi.org/10.1107/S2056989015004351
_version_ 1782372390503710720
author Downs, Emma L.
Zakharov, Lev N.
Tyler, David R.
author_facet Downs, Emma L.
Zakharov, Lev N.
Tyler, David R.
author_sort Downs, Emma L.
collection PubMed
description The mol­ecule of the title compound, [PtH(2)(C(6)H(18)N(3)P)(2)], has a centrosymmetric square-planar structure in which the Pt(II) atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt(II) atom sits on an inversion center and thus the asymmetric unit contains only half the mol­ecule. The Pt—P and Pt—H distances are 2.2574 (10) and 1.49 (7) Å, respectively.
format Online
Article
Text
id pubmed-4438795
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44387952015-05-30 Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II) Downs, Emma L. Zakharov, Lev N. Tyler, David R. Acta Crystallogr E Crystallogr Commun Data Reports The mol­ecule of the title compound, [PtH(2)(C(6)H(18)N(3)P)(2)], has a centrosymmetric square-planar structure in which the Pt(II) atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt(II) atom sits on an inversion center and thus the asymmetric unit contains only half the mol­ecule. The Pt—P and Pt—H distances are 2.2574 (10) and 1.49 (7) Å, respectively. International Union of Crystallography 2015-03-14 /pmc/articles/PMC4438795/ /pubmed/26029413 http://dx.doi.org/10.1107/S2056989015004351 Text en © Downs et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Downs, Emma L.
Zakharov, Lev N.
Tyler, David R.
Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title_full Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title_fullStr Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title_full_unstemmed Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title_short Crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κP]platinum(II)
title_sort crystal structure of trans-dihydrido­bis[tris­(di­methyl­amino)­phosphane-κp]platinum(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438795/
https://www.ncbi.nlm.nih.gov/pubmed/26029413
http://dx.doi.org/10.1107/S2056989015004351
work_keys_str_mv AT downsemmal crystalstructureoftransdihydridobistrisdimethylaminophosphanekpplatinumii
AT zakharovlevn crystalstructureoftransdihydridobistrisdimethylaminophosphanekpplatinumii
AT tylerdavidr crystalstructureoftransdihydridobistrisdimethylaminophosphanekpplatinumii

Ejemplares similares