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Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)

The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the mol­ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the i...

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Detalles Bibliográficos
Autores principales: Mohd Tajuddin, Amalina, Bahron, Hadariah, Mohd Zaki, Hamizah, Kassim, Karimah, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438801/
https://www.ncbi.nlm.nih.gov/pubmed/26029387
http://dx.doi.org/10.1107/S2056989015004405
Descripción
Sumario:The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the mol­ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd—N and Pd—O bond lengths of 2.028 (2) and 1.9770 (18) Å, respectively. The fluoro­phenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2 (2)° with the phenolate ring. In the crystal, mol­ecules are linked into chains along the [101] direction by weak C—H⋯O hydrogen bonds. Weak π–π inter­actions with centroid–centroid distances of 4.079 (2) Å stack the mol­ecules along c.