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Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)

The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the mol­ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the i...

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Autores principales: Mohd Tajuddin, Amalina, Bahron, Hadariah, Mohd Zaki, Hamizah, Kassim, Karimah, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438801/
https://www.ncbi.nlm.nih.gov/pubmed/26029387
http://dx.doi.org/10.1107/S2056989015004405
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author Mohd Tajuddin, Amalina
Bahron, Hadariah
Mohd Zaki, Hamizah
Kassim, Karimah
Chantrapromma, Suchada
author_facet Mohd Tajuddin, Amalina
Bahron, Hadariah
Mohd Zaki, Hamizah
Kassim, Karimah
Chantrapromma, Suchada
author_sort Mohd Tajuddin, Amalina
collection PubMed
description The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the mol­ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd—N and Pd—O bond lengths of 2.028 (2) and 1.9770 (18) Å, respectively. The fluoro­phenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2 (2)° with the phenolate ring. In the crystal, mol­ecules are linked into chains along the [101] direction by weak C—H⋯O hydrogen bonds. Weak π–π inter­actions with centroid–centroid distances of 4.079 (2) Å stack the mol­ecules along c.
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spelling pubmed-44388012015-05-30 Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II) Mohd Tajuddin, Amalina Bahron, Hadariah Mohd Zaki, Hamizah Kassim, Karimah Chantrapromma, Suchada Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the mol­ecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd—N and Pd—O bond lengths of 2.028 (2) and 1.9770 (18) Å, respectively. The fluoro­phenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2 (2)° with the phenolate ring. In the crystal, mol­ecules are linked into chains along the [101] direction by weak C—H⋯O hydrogen bonds. Weak π–π inter­actions with centroid–centroid distances of 4.079 (2) Å stack the mol­ecules along c. International Union of Crystallography 2015-03-11 /pmc/articles/PMC4438801/ /pubmed/26029387 http://dx.doi.org/10.1107/S2056989015004405 Text en © Mohd Tajuddin et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mohd Tajuddin, Amalina
Bahron, Hadariah
Mohd Zaki, Hamizah
Kassim, Karimah
Chantrapromma, Suchada
Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title_full Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title_fullStr Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title_full_unstemmed Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title_short Crystal structure of bis­(2-{1-[(E)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) N,O)palladium(II)
title_sort crystal structure of bis­(2-{1-[(e)-(4-fluoro­benz­yl)imino]­eth­yl}phenolato-κ(2) n,o)palladium(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438801/
https://www.ncbi.nlm.nih.gov/pubmed/26029387
http://dx.doi.org/10.1107/S2056989015004405
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