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Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2) N,O)palladium(II)
The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the molecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438801/ https://www.ncbi.nlm.nih.gov/pubmed/26029387 http://dx.doi.org/10.1107/S2056989015004405 |
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author | Mohd Tajuddin, Amalina Bahron, Hadariah Mohd Zaki, Hamizah Kassim, Karimah Chantrapromma, Suchada |
author_facet | Mohd Tajuddin, Amalina Bahron, Hadariah Mohd Zaki, Hamizah Kassim, Karimah Chantrapromma, Suchada |
author_sort | Mohd Tajuddin, Amalina |
collection | PubMed |
description | The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the molecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd—N and Pd—O bond lengths of 2.028 (2) and 1.9770 (18) Å, respectively. The fluorophenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2 (2)° with the phenolate ring. In the crystal, molecules are linked into chains along the [101] direction by weak C—H⋯O hydrogen bonds. Weak π–π interactions with centroid–centroid distances of 4.079 (2) Å stack the molecules along c. |
format | Online Article Text |
id | pubmed-4438801 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388012015-05-30 Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2) N,O)palladium(II) Mohd Tajuddin, Amalina Bahron, Hadariah Mohd Zaki, Hamizah Kassim, Karimah Chantrapromma, Suchada Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title complex, [Pd(C(15)H(13)FNO)(2)], contains one half of the molecule with the Pd(II) cation lying on an inversion centre and is coordinated by the bidentate Schiff base anion. The geometry around the cationic Pd(II) centre is distorted square planar, chelated by the imine N- and phenolate O-donor atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Pd—N and Pd—O bond lengths of 2.028 (2) and 1.9770 (18) Å, respectively. The fluorophenyl ring is tilted away from the coordination plane and makes a dihedral angle of 66.2 (2)° with the phenolate ring. In the crystal, molecules are linked into chains along the [101] direction by weak C—H⋯O hydrogen bonds. Weak π–π interactions with centroid–centroid distances of 4.079 (2) Å stack the molecules along c. International Union of Crystallography 2015-03-11 /pmc/articles/PMC4438801/ /pubmed/26029387 http://dx.doi.org/10.1107/S2056989015004405 Text en © Mohd Tajuddin et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Mohd Tajuddin, Amalina Bahron, Hadariah Mohd Zaki, Hamizah Kassim, Karimah Chantrapromma, Suchada Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2) N,O)palladium(II) |
title | Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
N,O)palladium(II) |
title_full | Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
N,O)palladium(II) |
title_fullStr | Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
N,O)palladium(II) |
title_full_unstemmed | Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
N,O)palladium(II) |
title_short | Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
N,O)palladium(II) |
title_sort | crystal structure of bis(2-{1-[(e)-(4-fluorobenzyl)imino]ethyl}phenolato-κ(2)
n,o)palladium(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438801/ https://www.ncbi.nlm.nih.gov/pubmed/26029387 http://dx.doi.org/10.1107/S2056989015004405 |
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