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Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II)
In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetrahedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle betwee...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438808/ https://www.ncbi.nlm.nih.gov/pubmed/26029409 http://dx.doi.org/10.1107/S2056989015003862 |
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author | Son, Kyung-sun Woo, Jeong Oh Kim, Daeyoung Kang, Sung Kwon |
author_facet | Son, Kyung-sun Woo, Jeong Oh Kim, Daeyoung Kang, Sung Kwon |
author_sort | Son, Kyung-sun |
collection | PubMed |
description | In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetrahedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle between Cl/Co/Cl and N/Co/N planes is 86.83 (7)°. The chelate ring has the conformation of a distorted boat. The dihedral angle between pyridyl ring and the coordinated pyrazolyl ring is 56.16 (12)°. The uncoordinated pyrazolyl ring is almost perpendicular to the pyridyl ring with the dihedral angle of 87.49 (10)°. In the crystal packing, intermolecular phenyl-C—H ⋯π(pyridyl) interactions generate dimeric aggregates. These are connected into a zigzag supramolecular chain along the c-axis direction via π–π interactions [inter-centroid distance between pyridyl and phenyl rings = 3.664 (2) Å]. |
format | Online Article Text |
id | pubmed-4438808 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388082015-05-30 Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) Son, Kyung-sun Woo, Jeong Oh Kim, Daeyoung Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetrahedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle between Cl/Co/Cl and N/Co/N planes is 86.83 (7)°. The chelate ring has the conformation of a distorted boat. The dihedral angle between pyridyl ring and the coordinated pyrazolyl ring is 56.16 (12)°. The uncoordinated pyrazolyl ring is almost perpendicular to the pyridyl ring with the dihedral angle of 87.49 (10)°. In the crystal packing, intermolecular phenyl-C—H ⋯π(pyridyl) interactions generate dimeric aggregates. These are connected into a zigzag supramolecular chain along the c-axis direction via π–π interactions [inter-centroid distance between pyridyl and phenyl rings = 3.664 (2) Å]. International Union of Crystallography 2015-03-04 /pmc/articles/PMC4438808/ /pubmed/26029409 http://dx.doi.org/10.1107/S2056989015003862 Text en © Son et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Son, Kyung-sun Woo, Jeong Oh Kim, Daeyoung Kang, Sung Kwon Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title | Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title_full | Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title_fullStr | Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title_full_unstemmed | Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title_short | Crystal structure of dichlorido{2,6-bis[(3-phenyl-1H-pyrazol-1-yl)methyl]pyridine}cobalt(II) |
title_sort | crystal structure of dichlorido{2,6-bis[(3-phenyl-1h-pyrazol-1-yl)methyl]pyridine}cobalt(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438808/ https://www.ncbi.nlm.nih.gov/pubmed/26029409 http://dx.doi.org/10.1107/S2056989015003862 |
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