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Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)

In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetra­hedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle betwee...

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Autores principales: Son, Kyung-sun, Woo, Jeong Oh, Kim, Daeyoung, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438808/
https://www.ncbi.nlm.nih.gov/pubmed/26029409
http://dx.doi.org/10.1107/S2056989015003862
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author Son, Kyung-sun
Woo, Jeong Oh
Kim, Daeyoung
Kang, Sung Kwon
author_facet Son, Kyung-sun
Woo, Jeong Oh
Kim, Daeyoung
Kang, Sung Kwon
author_sort Son, Kyung-sun
collection PubMed
description In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetra­hedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle between Cl/Co/Cl and N/Co/N planes is 86.83 (7)°. The chelate ring has the conformation of a distorted boat. The dihedral angle between pyridyl ring and the coordinated pyrazolyl ring is 56.16 (12)°. The uncoordinated pyrazolyl ring is almost perpendicular to the pyridyl ring with the dihedral angle of 87.49 (10)°. In the crystal packing, inter­molecular phenyl-C—H ⋯π(pyrid­yl) inter­actions generate dimeric aggregates. These are connected into a zigzag supra­molecular chain along the c-axis direction via π–π inter­actions [inter-centroid distance between pyridyl and phenyl rings = 3.664 (2) Å].
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spelling pubmed-44388082015-05-30 Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II) Son, Kyung-sun Woo, Jeong Oh Kim, Daeyoung Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [CoCl(2)(C(25)H(21)N(5))], the Co(II) atom is coordinated by two Cl atoms and two N atoms, provided by a tridentate pyrazolylpyridyl ligand, forming a slightly distorted tetra­hedral geometry [range of angles: 96.51 (10) (chelate ring) to 118.60 (9)°]. The dihedral angle between Cl/Co/Cl and N/Co/N planes is 86.83 (7)°. The chelate ring has the conformation of a distorted boat. The dihedral angle between pyridyl ring and the coordinated pyrazolyl ring is 56.16 (12)°. The uncoordinated pyrazolyl ring is almost perpendicular to the pyridyl ring with the dihedral angle of 87.49 (10)°. In the crystal packing, inter­molecular phenyl-C—H ⋯π(pyrid­yl) inter­actions generate dimeric aggregates. These are connected into a zigzag supra­molecular chain along the c-axis direction via π–π inter­actions [inter-centroid distance between pyridyl and phenyl rings = 3.664 (2) Å]. International Union of Crystallography 2015-03-04 /pmc/articles/PMC4438808/ /pubmed/26029409 http://dx.doi.org/10.1107/S2056989015003862 Text en © Son et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Son, Kyung-sun
Woo, Jeong Oh
Kim, Daeyoung
Kang, Sung Kwon
Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title_full Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title_fullStr Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title_full_unstemmed Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title_short Crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1H-pyrazol-1-yl)meth­yl]pyridine}cobalt(II)
title_sort crystal structure of di­chlorido­{2,6-bis­[(3-phenyl-1h-pyrazol-1-yl)meth­yl]pyridine}cobalt(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438808/
https://www.ncbi.nlm.nih.gov/pubmed/26029409
http://dx.doi.org/10.1107/S2056989015003862
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