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Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)

The asymmetric unit of the title compound, [Pt(C(10)H(5)F(2)N(2))(C(5)H(7)O(2))], comprises one Pt(II) atom, one 2,6-di­fluoro-2,3-bi­pyridine ligand and one acetyl­acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di­fluoro-3-(pyr...

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Detalles Bibliográficos
Autores principales: Park, Ki-Min, Lee, Jieun, Kang, Youngjin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438810/
https://www.ncbi.nlm.nih.gov/pubmed/26029388
http://dx.doi.org/10.1107/S2056989015004375
Descripción
Sumario:The asymmetric unit of the title compound, [Pt(C(10)H(5)F(2)N(2))(C(5)H(7)O(2))], comprises one Pt(II) atom, one 2,6-di­fluoro-2,3-bi­pyridine ligand and one acetyl­acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di­fluoro-3-(pyridin-2-yl)pyridin-4-yl ligand and O,O′-chelated by the pentane-2,4-dionate ligand. The two pyridine rings of the bi­pyridine ligand are approximately coplanar, making a dihedral angle of 1.2 (2)°. A variety of intra- and inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, as well as π–π inter­actions [centroid–centroid distances = 4.337 (3) and 3.774 (3) Å] contribute to the stabilization of the mol­ecular and crystal structures, and result in the formation of a three-dimensional supra­molecular framework.