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Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)

The asymmetric unit of the title compound, [Pt(C(10)H(5)F(2)N(2))(C(5)H(7)O(2))], comprises one Pt(II) atom, one 2,6-di­fluoro-2,3-bi­pyridine ligand and one acetyl­acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di­fluoro-3-(pyr...

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Autores principales: Park, Ki-Min, Lee, Jieun, Kang, Youngjin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438810/
https://www.ncbi.nlm.nih.gov/pubmed/26029388
http://dx.doi.org/10.1107/S2056989015004375
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author Park, Ki-Min
Lee, Jieun
Kang, Youngjin
author_facet Park, Ki-Min
Lee, Jieun
Kang, Youngjin
author_sort Park, Ki-Min
collection PubMed
description The asymmetric unit of the title compound, [Pt(C(10)H(5)F(2)N(2))(C(5)H(7)O(2))], comprises one Pt(II) atom, one 2,6-di­fluoro-2,3-bi­pyridine ligand and one acetyl­acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di­fluoro-3-(pyridin-2-yl)pyridin-4-yl ligand and O,O′-chelated by the pentane-2,4-dionate ligand. The two pyridine rings of the bi­pyridine ligand are approximately coplanar, making a dihedral angle of 1.2 (2)°. A variety of intra- and inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, as well as π–π inter­actions [centroid–centroid distances = 4.337 (3) and 3.774 (3) Å] contribute to the stabilization of the mol­ecular and crystal structures, and result in the formation of a three-dimensional supra­molecular framework.
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spelling pubmed-44388102015-05-30 Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II) Park, Ki-Min Lee, Jieun Kang, Youngjin Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Pt(C(10)H(5)F(2)N(2))(C(5)H(7)O(2))], comprises one Pt(II) atom, one 2,6-di­fluoro-2,3-bi­pyridine ligand and one acetyl­acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di­fluoro-3-(pyridin-2-yl)pyridin-4-yl ligand and O,O′-chelated by the pentane-2,4-dionate ligand. The two pyridine rings of the bi­pyridine ligand are approximately coplanar, making a dihedral angle of 1.2 (2)°. A variety of intra- and inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, as well as π–π inter­actions [centroid–centroid distances = 4.337 (3) and 3.774 (3) Å] contribute to the stabilization of the mol­ecular and crystal structures, and result in the formation of a three-dimensional supra­molecular framework. International Union of Crystallography 2015-03-11 /pmc/articles/PMC4438810/ /pubmed/26029388 http://dx.doi.org/10.1107/S2056989015004375 Text en © Park et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Park, Ki-Min
Lee, Jieun
Kang, Youngjin
Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title_full Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title_fullStr Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title_full_unstemmed Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title_short Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](pentane-2,4-dionato-κ(2) O,O′)platinum(II)
title_sort crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κn)pyridin-4-yl-κc (4)](pentane-2,4-dionato-κ(2) o,o′)platinum(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438810/
https://www.ncbi.nlm.nih.gov/pubmed/26029388
http://dx.doi.org/10.1107/S2056989015004375
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