Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate

The cation of the complex title salt, [Zn(C(13)H(11)N(3))(2)(H(2)O)](NO(3))(2), lies about a twofold rotation axis, which passes through the Zn(II) atom and the O atom of the aqua ligand. The Zn(II) atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angl...

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Detalles Bibliográficos
Autores principales: Kim, Yongtae, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438813/
https://www.ncbi.nlm.nih.gov/pubmed/26029414
http://dx.doi.org/10.1107/S2056989015004636
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author Kim, Yongtae
Kang, Sung Kwon
author_facet Kim, Yongtae
Kang, Sung Kwon
author_sort Kim, Yongtae
collection PubMed
description The cation of the complex title salt, [Zn(C(13)H(11)N(3))(2)(H(2)O)](NO(3))(2), lies about a twofold rotation axis, which passes through the Zn(II) atom and the O atom of the aqua ligand. The Zn(II) atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)°], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)–122.42 (3)°]. The dihedral angle between the imidazole and aniline rings is 23.86 (5)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network.
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spelling pubmed-44388132015-05-30 Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate Kim, Yongtae Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports The cation of the complex title salt, [Zn(C(13)H(11)N(3))(2)(H(2)O)](NO(3))(2), lies about a twofold rotation axis, which passes through the Zn(II) atom and the O atom of the aqua ligand. The Zn(II) atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)°], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)–122.42 (3)°]. The dihedral angle between the imidazole and aniline rings is 23.86 (5)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. International Union of Crystallography 2015-03-14 /pmc/articles/PMC4438813/ /pubmed/26029414 http://dx.doi.org/10.1107/S2056989015004636 Text en © Kim and Kang 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kim, Yongtae
Kang, Sung Kwon
Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title_full Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title_fullStr Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title_full_unstemmed Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title_short Crystal structure of aqua­bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]zinc dinitrate
title_sort crystal structure of aqua­bis­[2-(1h-benzimidazol-2-yl-κn (3))aniline-κn]zinc dinitrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438813/
https://www.ncbi.nlm.nih.gov/pubmed/26029414
http://dx.doi.org/10.1107/S2056989015004636
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