Crystal structure of ruthenocenecarbo­nitrile

The mol­ecular structure of ruthenocenecarbo­nitrile, [Ru(η(5)-C(5)H(4)C N)(η(5)-C(5)H(5))], exhibits point group symmetry m, with the mirror plane bis­ecting the mol­ecule through the C N substituent. The Ru(II) atom is slightly shifted from the η(5)-C(5)H(4) centroid towards the C N substituent. I...

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Detalles Bibliográficos
Autores principales: Strehler, Frank, Korb, Marcus, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438815/
https://www.ncbi.nlm.nih.gov/pubmed/26029400
http://dx.doi.org/10.1107/S205698901500540X
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author Strehler, Frank
Korb, Marcus
Lang, Heinrich
author_facet Strehler, Frank
Korb, Marcus
Lang, Heinrich
author_sort Strehler, Frank
collection PubMed
description The mol­ecular structure of ruthenocenecarbo­nitrile, [Ru(η(5)-C(5)H(4)C N)(η(5)-C(5)H(5))], exhibits point group symmetry m, with the mirror plane bis­ecting the mol­ecule through the C N substituent. The Ru(II) atom is slightly shifted from the η(5)-C(5)H(4) centroid towards the C N substituent. In the crystal, mol­ecules are arranged in columns parallel to [100]. One-dimensional inter­molecular π–π inter­actions [3.363 (3) Å] between the C N carbon atom and one carbon of the cyclo­penta­dienyl ring of the overlaying mol­ecule are present.
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spelling pubmed-44388152015-05-30 Crystal structure of ruthenocenecarbo­nitrile Strehler, Frank Korb, Marcus Lang, Heinrich Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of ruthenocenecarbo­nitrile, [Ru(η(5)-C(5)H(4)C N)(η(5)-C(5)H(5))], exhibits point group symmetry m, with the mirror plane bis­ecting the mol­ecule through the C N substituent. The Ru(II) atom is slightly shifted from the η(5)-C(5)H(4) centroid towards the C N substituent. In the crystal, mol­ecules are arranged in columns parallel to [100]. One-dimensional inter­molecular π–π inter­actions [3.363 (3) Å] between the C N carbon atom and one carbon of the cyclo­penta­dienyl ring of the overlaying mol­ecule are present. International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438815/ /pubmed/26029400 http://dx.doi.org/10.1107/S205698901500540X Text en © Strehler et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Strehler, Frank
Korb, Marcus
Lang, Heinrich
Crystal structure of ruthenocenecarbo­nitrile
title Crystal structure of ruthenocenecarbo­nitrile
title_full Crystal structure of ruthenocenecarbo­nitrile
title_fullStr Crystal structure of ruthenocenecarbo­nitrile
title_full_unstemmed Crystal structure of ruthenocenecarbo­nitrile
title_short Crystal structure of ruthenocenecarbo­nitrile
title_sort crystal structure of ruthenocenecarbo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438815/
https://www.ncbi.nlm.nih.gov/pubmed/26029400
http://dx.doi.org/10.1107/S205698901500540X
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AT korbmarcus crystalstructureofruthenocenecarbonitrile
AT langheinrich crystalstructureofruthenocenecarbonitrile

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