Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)

Thermally unstable Xe(SO(3)F)(2) has been prepared by the reaction of XeF(2) with HSO(3)F. Single crystals were obtained from HSO(3)F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an al...

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Detalles Bibliográficos
Autores principales: Malischewski, Moritz, Seppelt, Konrad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438818/
https://www.ncbi.nlm.nih.gov/pubmed/26029391
http://dx.doi.org/10.1107/S2056989015004788
Descripción
Sumario:Thermally unstable Xe(SO(3)F)(2) has been prepared by the reaction of XeF(2) with HSO(3)F. Single crystals were obtained from HSO(3)F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an almost linear fashion [O—Xe—O = 179.13 (4)°]. The crystal packing is strongly influenced by inter­molecular van der Waals forces.

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