Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)

Thermally unstable Xe(SO(3)F)(2) has been prepared by the reaction of XeF(2) with HSO(3)F. Single crystals were obtained from HSO(3)F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an al...

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Autores principales: Malischewski, Moritz, Seppelt, Konrad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438818/
https://www.ncbi.nlm.nih.gov/pubmed/26029391
http://dx.doi.org/10.1107/S2056989015004788
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author Malischewski, Moritz
Seppelt, Konrad
author_facet Malischewski, Moritz
Seppelt, Konrad
author_sort Malischewski, Moritz
collection PubMed
description Thermally unstable Xe(SO(3)F)(2) has been prepared by the reaction of XeF(2) with HSO(3)F. Single crystals were obtained from HSO(3)F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an almost linear fashion [O—Xe—O = 179.13 (4)°]. The crystal packing is strongly influenced by inter­molecular van der Waals forces.
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spelling pubmed-44388182015-05-30 Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2) Malischewski, Moritz Seppelt, Konrad Acta Crystallogr E Crystallogr Commun Research Communications Thermally unstable Xe(SO(3)F)(2) has been prepared by the reaction of XeF(2) with HSO(3)F. Single crystals were obtained from HSO(3)F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an almost linear fashion [O—Xe—O = 179.13 (4)°]. The crystal packing is strongly influenced by inter­molecular van der Waals forces. International Union of Crystallography 2015-03-14 /pmc/articles/PMC4438818/ /pubmed/26029391 http://dx.doi.org/10.1107/S2056989015004788 Text en © Malischewski and Seppelt 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Malischewski, Moritz
Seppelt, Konrad
Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title_full Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title_fullStr Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title_full_unstemmed Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title_short Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO(3)F)(2)
title_sort crystal structure of bis­(fluoro­sulfato-κo)xenon(ii), xe(so(3)f)(2)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438818/
https://www.ncbi.nlm.nih.gov/pubmed/26029391
http://dx.doi.org/10.1107/S2056989015004788
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