Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide

In the title compound, C(10)H(14)N(2)O, the pyridine ring is inclined to the mean plane of the amide moiety [N—C(=O)C] by 17.60 (8)°. There is an intra­molecular C—H⋯O hydrogen bond present involving the carbonyl O atom. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains...

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Autores principales: El-Hiti, Gamal A., Smith, Keith, Hegazy, Amany S., Alanazi, Saud A., Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438820/
https://www.ncbi.nlm.nih.gov/pubmed/26029437
http://dx.doi.org/10.1107/S2056989015005289
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author El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
author_facet El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
author_sort El-Hiti, Gamal A.
collection PubMed
description In the title compound, C(10)H(14)N(2)O, the pyridine ring is inclined to the mean plane of the amide moiety [N—C(=O)C] by 17.60 (8)°. There is an intra­molecular C—H⋯O hydrogen bond present involving the carbonyl O atom. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along [100]. The tert-butyl group is disordered over two sets of sites with a refined occupancy ratio of 0.758 (12):0.242 (12).
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spelling pubmed-44388202015-05-30 Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide El-Hiti, Gamal A. Smith, Keith Hegazy, Amany S. Alanazi, Saud A. Kariuki, Benson M. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(10)H(14)N(2)O, the pyridine ring is inclined to the mean plane of the amide moiety [N—C(=O)C] by 17.60 (8)°. There is an intra­molecular C—H⋯O hydrogen bond present involving the carbonyl O atom. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along [100]. The tert-butyl group is disordered over two sets of sites with a refined occupancy ratio of 0.758 (12):0.242 (12). International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438820/ /pubmed/26029437 http://dx.doi.org/10.1107/S2056989015005289 Text en © El-Hiti et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alanazi, Saud A.
Kariuki, Benson M.
Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title_full Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title_fullStr Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title_full_unstemmed Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title_short Crystal structure of 2,2-dimethyl-N-(pyridin-3-yl)propanamide
title_sort crystal structure of 2,2-dimethyl-n-(pyridin-3-yl)propanamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438820/
https://www.ncbi.nlm.nih.gov/pubmed/26029437
http://dx.doi.org/10.1107/S2056989015005289
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