Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)

The title complex, [Cu(C(22)H(19)N(2)O(3)S(2))(2)], was obtained from the reaction between (Z)-methyl 2-(5-benzyl­imino-4-benzyl­carbamo­thioyl-3-oxo­thio­lan-2-yl­idene)acetate and Cu(NO(3))(2). The Cu(II) atom is tetra­coordinated by two N,S-bidentate ligands, forming a highly distorted tetra­hedr...

Descripción completa

Detalles Bibliográficos
Autores principales: Obydennov, Konstantin, Khamidullina, Liliya, Slepukhin, Pavel, Morzherin, Yury
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438821/
https://www.ncbi.nlm.nih.gov/pubmed/26029418
http://dx.doi.org/10.1107/S2056989015005022
_version_ 1782372396581257216
author Obydennov, Konstantin
Khamidullina, Liliya
Slepukhin, Pavel
Morzherin, Yury
author_facet Obydennov, Konstantin
Khamidullina, Liliya
Slepukhin, Pavel
Morzherin, Yury
author_sort Obydennov, Konstantin
collection PubMed
description The title complex, [Cu(C(22)H(19)N(2)O(3)S(2))(2)], was obtained from the reaction between (Z)-methyl 2-(5-benzyl­imino-4-benzyl­carbamo­thioyl-3-oxo­thio­lan-2-yl­idene)acetate and Cu(NO(3))(2). The Cu(II) atom is tetra­coordinated by two N,S-bidentate ligands, forming a highly distorted tetra­hedral environment. The structure displays two intra­molecular N—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-4438821
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44388212015-05-30 Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II) Obydennov, Konstantin Khamidullina, Liliya Slepukhin, Pavel Morzherin, Yury Acta Crystallogr E Crystallogr Commun Data Reports The title complex, [Cu(C(22)H(19)N(2)O(3)S(2))(2)], was obtained from the reaction between (Z)-methyl 2-(5-benzyl­imino-4-benzyl­carbamo­thioyl-3-oxo­thio­lan-2-yl­idene)acetate and Cu(NO(3))(2). The Cu(II) atom is tetra­coordinated by two N,S-bidentate ligands, forming a highly distorted tetra­hedral environment. The structure displays two intra­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438821/ /pubmed/26029418 http://dx.doi.org/10.1107/S2056989015005022 Text en © Obydennov et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Obydennov, Konstantin
Khamidullina, Liliya
Slepukhin, Pavel
Morzherin, Yury
Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title_full Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title_fullStr Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title_full_unstemmed Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title_short Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)
title_sort crystal structure of bis­{(z)-(benzyl­amino)[(5z)-2-(benzyl­imino-κn)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κs}copper(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438821/
https://www.ncbi.nlm.nih.gov/pubmed/26029418
http://dx.doi.org/10.1107/S2056989015005022
work_keys_str_mv AT obydennovkonstantin crystalstructureofbiszbenzylamino5z2benzyliminokn52methoxy2oxoethylidene4oxothiolan3ylidenemethanethiolatokscopperii
AT khamidullinaliliya crystalstructureofbiszbenzylamino5z2benzyliminokn52methoxy2oxoethylidene4oxothiolan3ylidenemethanethiolatokscopperii
AT slepukhinpavel crystalstructureofbiszbenzylamino5z2benzyliminokn52methoxy2oxoethylidene4oxothiolan3ylidenemethanethiolatokscopperii
AT morzherinyury crystalstructureofbiszbenzylamino5z2benzyliminokn52methoxy2oxoethylidene4oxothiolan3ylidenemethanethiolatokscopperii

Ejemplares similares