Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate

The title compound, C(17)H(15)N(5)O(4), was obtained via the condensation of 3-eth­oxy-2-[2-(4-nitro­phen­yl)hydrazono]-3-oxo­propanoic acid with 1,2-di­amino­benzene. In the mol­ecule, the dihedral angles between the acetate group and the two aromatic subunits (benzimidazole and nitro­phenyl­hydraz...

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Autores principales: Loughzail, Mohamed, Baouid, Abdesselam, El Ammari, Lahcen, Saadi, Mohamed, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438822/
https://www.ncbi.nlm.nih.gov/pubmed/26029432
http://dx.doi.org/10.1107/S2056989015004818
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author Loughzail, Mohamed
Baouid, Abdesselam
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_facet Loughzail, Mohamed
Baouid, Abdesselam
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_sort Loughzail, Mohamed
collection PubMed
description The title compound, C(17)H(15)N(5)O(4), was obtained via the condensation of 3-eth­oxy-2-[2-(4-nitro­phen­yl)hydrazono]-3-oxo­propanoic acid with 1,2-di­amino­benzene. In the mol­ecule, the dihedral angles between the acetate group and the two aromatic subunits (benzimidazole and nitro­phenyl­hydrazone) are 7.35 (9) and 18.23 (9)°, respectively. Intra­molecular N—H⋯O and N—H⋯N contacts occur. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into chains along the b-axis direction.
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spelling pubmed-44388222015-05-30 Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate Loughzail, Mohamed Baouid, Abdesselam El Ammari, Lahcen Saadi, Mohamed Berraho, Moha Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(17)H(15)N(5)O(4), was obtained via the condensation of 3-eth­oxy-2-[2-(4-nitro­phen­yl)hydrazono]-3-oxo­propanoic acid with 1,2-di­amino­benzene. In the mol­ecule, the dihedral angles between the acetate group and the two aromatic subunits (benzimidazole and nitro­phenyl­hydrazone) are 7.35 (9) and 18.23 (9)°, respectively. Intra­molecular N—H⋯O and N—H⋯N contacts occur. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into chains along the b-axis direction. International Union of Crystallography 2015-03-14 /pmc/articles/PMC4438822/ /pubmed/26029432 http://dx.doi.org/10.1107/S2056989015004818 Text en © Loughzail et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Loughzail, Mohamed
Baouid, Abdesselam
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title_full Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title_fullStr Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title_full_unstemmed Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title_short Crystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
title_sort crystal structure of ethyl 2-(1h-benzimidazol-2-yl)-2-[2-(4-nitro­phen­yl)hydrazinyl­idene]acetate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438822/
https://www.ncbi.nlm.nih.gov/pubmed/26029432
http://dx.doi.org/10.1107/S2056989015004818
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