Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide

The title salt, [V(C(9)H(9)N)(7)](+)I(−) or [V(CNX­yl)(7)](+)I(−) (Xyl is 2,6-di­methyl­phen­yl), crystallized from tetra­hydro­furan at low temperatures after reacting (Et(4)N)(+)[V(CO)(6)](−), excess of CNXyl and iodine. The complex cation and the two crystallographically different iodide anions,...

Descripción completa

Detalles Bibliográficos
Autores principales: Minyaev, Mikhail E., Ellis, John E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438829/
https://www.ncbi.nlm.nih.gov/pubmed/26029408
http://dx.doi.org/10.1107/S2056989015006015
_version_ 1782372398442479616
author Minyaev, Mikhail E.
Ellis, John E.
author_facet Minyaev, Mikhail E.
Ellis, John E.
author_sort Minyaev, Mikhail E.
collection PubMed
description The title salt, [V(C(9)H(9)N)(7)](+)I(−) or [V(CNX­yl)(7)](+)I(−) (Xyl is 2,6-di­methyl­phen­yl), crystallized from tetra­hydro­furan at low temperatures after reacting (Et(4)N)(+)[V(CO)(6)](−), excess of CNXyl and iodine. The complex cation and the two crystallographically different iodide anions, each located on a different glide plane, are well separated in the crystal structure. The V(CN)(7) core of the cation has the form of a distorted monocapped trigonal prism. This compound is of inter­est as the first isolable homoleptic seven-coordinate vanadium analog of the 18-electron [V(CO)(7)](+) monocation.
format Online
Article
Text
id pubmed-4438829
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44388292015-05-30 Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide Minyaev, Mikhail E. Ellis, John E. Acta Crystallogr E Crystallogr Commun Research Communications The title salt, [V(C(9)H(9)N)(7)](+)I(−) or [V(CNX­yl)(7)](+)I(−) (Xyl is 2,6-di­methyl­phen­yl), crystallized from tetra­hydro­furan at low temperatures after reacting (Et(4)N)(+)[V(CO)(6)](−), excess of CNXyl and iodine. The complex cation and the two crystallographically different iodide anions, each located on a different glide plane, are well separated in the crystal structure. The V(CN)(7) core of the cation has the form of a distorted monocapped trigonal prism. This compound is of inter­est as the first isolable homoleptic seven-coordinate vanadium analog of the 18-electron [V(CO)(7)](+) monocation. International Union of Crystallography 2015-03-28 /pmc/articles/PMC4438829/ /pubmed/26029408 http://dx.doi.org/10.1107/S2056989015006015 Text en © Minyaev and Ellis 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Minyaev, Mikhail E.
Ellis, John E.
Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title_full Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title_fullStr Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title_full_unstemmed Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title_short Crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κC)vanadium(I) iodide
title_sort crystal structure of hepta­kis­(2,6-di­methyl­phenyl isocyanide-κc)vanadium(i) iodide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438829/
https://www.ncbi.nlm.nih.gov/pubmed/26029408
http://dx.doi.org/10.1107/S2056989015006015
work_keys_str_mv AT minyaevmikhaile crystalstructureofheptakis26dimethylphenylisocyanidekcvanadiumiiodide
AT ellisjohne crystalstructureofheptakis26dimethylphenylisocyanidekcvanadiumiiodide

Ejemplares similares