Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate

The title complex, [PtCl(C(14)H(23)N(5))]Cl·2H(2)O, is isomorphous with the Pd(II) compound characterized previously [Mendoza, Bernès & Mendoza-Díaz (2006 ▸). Acta Cryst. E62, m2934–m2936]. The angle between pyrazole mean planes in the main ligand is 88.3 (4)°, similar to that observed in the Pd...

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Autores principales: Mendoza, María de los Angeles, Bernès, Sylvain, Mendoza-Díaz, Guillermo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438831/
https://www.ncbi.nlm.nih.gov/pubmed/26029421
http://dx.doi.org/10.1107/S2056989015005307
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author Mendoza, María de los Angeles
Bernès, Sylvain
Mendoza-Díaz, Guillermo
author_facet Mendoza, María de los Angeles
Bernès, Sylvain
Mendoza-Díaz, Guillermo
author_sort Mendoza, María de los Angeles
collection PubMed
description The title complex, [PtCl(C(14)H(23)N(5))]Cl·2H(2)O, is isomorphous with the Pd(II) compound characterized previously [Mendoza, Bernès & Mendoza-Díaz (2006 ▸). Acta Cryst. E62, m2934–m2936]. The angle between pyrazole mean planes in the main ligand is 88.3 (4)°, similar to that observed in the Pd(II) analogue [87.62 (11)°]. This tridentate ligand adopts a conformation approximating a twofold symmetry, allowing its coordination to the metal atom, together with a chloride ligand, in an almost perfect square-planar geometry. A chloride anion and two water mol­ecules in the asymmetric unit form a hydrogen-bonded network connected to the complex mol­ecules in the crystal via the NH amine groups, forming chains along [100].
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spelling pubmed-44388312015-05-30 Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate Mendoza, María de los Angeles Bernès, Sylvain Mendoza-Díaz, Guillermo Acta Crystallogr E Crystallogr Commun Data Reports The title complex, [PtCl(C(14)H(23)N(5))]Cl·2H(2)O, is isomorphous with the Pd(II) compound characterized previously [Mendoza, Bernès & Mendoza-Díaz (2006 ▸). Acta Cryst. E62, m2934–m2936]. The angle between pyrazole mean planes in the main ligand is 88.3 (4)°, similar to that observed in the Pd(II) analogue [87.62 (11)°]. This tridentate ligand adopts a conformation approximating a twofold symmetry, allowing its coordination to the metal atom, together with a chloride ligand, in an almost perfect square-planar geometry. A chloride anion and two water mol­ecules in the asymmetric unit form a hydrogen-bonded network connected to the complex mol­ecules in the crystal via the NH amine groups, forming chains along [100]. International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438831/ /pubmed/26029421 http://dx.doi.org/10.1107/S2056989015005307 Text en © Mendoza et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mendoza, María de los Angeles
Bernès, Sylvain
Mendoza-Díaz, Guillermo
Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title_full Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title_fullStr Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title_full_unstemmed Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title_short Crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κN (2))eth­yl]amine-κN}chlorido­platinum(II) chloride dihydrate
title_sort crystal structure of {bis­[2-(3,5-di­methyl­pyrazol-1-yl-κn (2))eth­yl]amine-κn}chlorido­platinum(ii) chloride dihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438831/
https://www.ncbi.nlm.nih.gov/pubmed/26029421
http://dx.doi.org/10.1107/S2056989015005307
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AT mendozadiazguillermo crystalstructureofbis235dimethylpyrazol1ylkn2ethylamineknchloridoplatinumiichloridedihydrate

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