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Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438834/ https://www.ncbi.nlm.nih.gov/pubmed/26029411 http://dx.doi.org/10.1107/S2056989015004120 |
Sumario: | In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network. |
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