Cargando…
Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438834/ https://www.ncbi.nlm.nih.gov/pubmed/26029411 http://dx.doi.org/10.1107/S2056989015004120 |
_version_ | 1782372399616884736 |
---|---|
author | Kim, Daeyoung Kang, Sung Kwon |
author_facet | Kim, Daeyoung Kang, Sung Kwon |
author_sort | Kim, Daeyoung |
collection | PubMed |
description | In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network. |
format | Online Article Text |
id | pubmed-4438834 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388342015-05-30 Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate] Kim, Daeyoung Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network. International Union of Crystallography 2015-03-07 /pmc/articles/PMC4438834/ /pubmed/26029411 http://dx.doi.org/10.1107/S2056989015004120 Text en © Kim and Kang 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Kim, Daeyoung Kang, Sung Kwon Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate] |
title | Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3)
N
(1),N
(2):N
(2′)}] nitrate] |
title_full | Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3)
N
(1),N
(2):N
(2′)}] nitrate] |
title_fullStr | Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3)
N
(1),N
(2):N
(2′)}] nitrate] |
title_full_unstemmed | Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3)
N
(1),N
(2):N
(2′)}] nitrate] |
title_short | Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine-κ(3)
N
(1),N
(2):N
(2′)}] nitrate] |
title_sort | crystal structure of catena-poly[[silver(i)-{μ-2,6-bis[(1h-pyrazol-1-yl)methyl]pyridine-κ(3)
n
(1),n
(2):n
(2′)}] nitrate] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438834/ https://www.ncbi.nlm.nih.gov/pubmed/26029411 http://dx.doi.org/10.1107/S2056989015004120 |
work_keys_str_mv | AT kimdaeyoung crystalstructureofcatenapolysilverim26bis1hpyrazol1ylmethylpyridinek3n1n2n2nitrate AT kangsungkwon crystalstructureofcatenapolysilverim26bis1hpyrazol1ylmethylpyridinek3n1n2n2nitrate |