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Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]

In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat...

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Autores principales: Kim, Daeyoung, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438834/
https://www.ncbi.nlm.nih.gov/pubmed/26029411
http://dx.doi.org/10.1107/S2056989015004120
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author Kim, Daeyoung
Kang, Sung Kwon
author_facet Kim, Daeyoung
Kang, Sung Kwon
author_sort Kim, Daeyoung
collection PubMed
description In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network.
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spelling pubmed-44388342015-05-30 Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate] Kim, Daeyoung Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, {[Ag(C(13)H(13)N(5))]NO(3)}(n), the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network. International Union of Crystallography 2015-03-07 /pmc/articles/PMC4438834/ /pubmed/26029411 http://dx.doi.org/10.1107/S2056989015004120 Text en © Kim and Kang 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kim, Daeyoung
Kang, Sung Kwon
Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title_full Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title_fullStr Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title_full_unstemmed Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title_short Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis­[(1H-pyrazol-1-yl)meth­yl]pyridine-κ(3) N (1),N (2):N (2′)}] nitrate]
title_sort crystal structure of catena-poly[[silver(i)-{μ-2,6-bis­[(1h-pyrazol-1-yl)meth­yl]pyridine-κ(3) n (1),n (2):n (2′)}] nitrate]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438834/
https://www.ncbi.nlm.nih.gov/pubmed/26029411
http://dx.doi.org/10.1107/S2056989015004120
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