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Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-diyl)bis[1H-imidazole-2(3H)-thione]
In the title compound, C(17)H(21)N(5)S(2), the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438837/ https://www.ncbi.nlm.nih.gov/pubmed/26029442 http://dx.doi.org/10.1107/S2056989015005642 |
Sumario: | In the title compound, C(17)H(21)N(5)S(2), the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, molecules are linked by weak C—H⋯S interactions, generating C(5) chains propagating along [001]. |
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