Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]

In the title compound, C(17)H(21)N(5)S(2), the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N...

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Detalles Bibliográficos
Autores principales: Sun, Ying, Wang, Hui, Jia, Wei-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438837/
https://www.ncbi.nlm.nih.gov/pubmed/26029442
http://dx.doi.org/10.1107/S2056989015005642
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author Sun, Ying
Wang, Hui
Jia, Wei-Guo
author_facet Sun, Ying
Wang, Hui
Jia, Wei-Guo
author_sort Sun, Ying
collection PubMed
description In the title compound, C(17)H(21)N(5)S(2), the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, mol­ecules are linked by weak C—H⋯S inter­actions, generating C(5) chains propagating along [001].
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spelling pubmed-44388372015-05-30 Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione] Sun, Ying Wang, Hui Jia, Wei-Guo Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(21)N(5)S(2), the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, mol­ecules are linked by weak C—H⋯S inter­actions, generating C(5) chains propagating along [001]. International Union of Crystallography 2015-03-25 /pmc/articles/PMC4438837/ /pubmed/26029442 http://dx.doi.org/10.1107/S2056989015005642 Text en © Sun et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sun, Ying
Wang, Hui
Jia, Wei-Guo
Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title_full Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title_fullStr Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title_full_unstemmed Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title_short Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1H-imidazole-2(3H)-thione]
title_sort crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-di­yl)bis­[1h-imidazole-2(3h)-thione]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438837/
https://www.ncbi.nlm.nih.gov/pubmed/26029442
http://dx.doi.org/10.1107/S2056989015005642
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