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Crystal structure of 9-methacryloylanthracene
In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methylprop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438842/ https://www.ncbi.nlm.nih.gov/pubmed/26029389 http://dx.doi.org/10.1107/S2056989015004090 |
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author | Agrahari, Aditya Wagers, Patrick O. Schildcrout, Steven M. Masnovi, John Youngs, Wiley J. |
author_facet | Agrahari, Aditya Wagers, Patrick O. Schildcrout, Steven M. Masnovi, John Youngs, Wiley J. |
author_sort | Agrahari, Aditya |
collection | PubMed |
description | In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methylprop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about the Csp (2)—Csp (2) bond in the side chain is transoid. In the crystal, the end rings of the anthryl units in adjacent molecules associate in parallel–planar orientations [shortest centroid–centroid distance = 3.6320 (7) Å]. A weak hydrogen bond is observed between an aromatic H atom and the O atom of a molecule displaced by translation in the a-axis direction, forming sheets of parallel-planar anthryl groups packing in this direction. |
format | Online Article Text |
id | pubmed-4438842 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388422015-05-30 Crystal structure of 9-methacryloylanthracene Agrahari, Aditya Wagers, Patrick O. Schildcrout, Steven M. Masnovi, John Youngs, Wiley J. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methylprop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about the Csp (2)—Csp (2) bond in the side chain is transoid. In the crystal, the end rings of the anthryl units in adjacent molecules associate in parallel–planar orientations [shortest centroid–centroid distance = 3.6320 (7) Å]. A weak hydrogen bond is observed between an aromatic H atom and the O atom of a molecule displaced by translation in the a-axis direction, forming sheets of parallel-planar anthryl groups packing in this direction. International Union of Crystallography 2015-03-11 /pmc/articles/PMC4438842/ /pubmed/26029389 http://dx.doi.org/10.1107/S2056989015004090 Text en © Agrahari et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Agrahari, Aditya Wagers, Patrick O. Schildcrout, Steven M. Masnovi, John Youngs, Wiley J. Crystal structure of 9-methacryloylanthracene |
title | Crystal structure of 9-methacryloylanthracene |
title_full | Crystal structure of 9-methacryloylanthracene |
title_fullStr | Crystal structure of 9-methacryloylanthracene |
title_full_unstemmed | Crystal structure of 9-methacryloylanthracene |
title_short | Crystal structure of 9-methacryloylanthracene |
title_sort | crystal structure of 9-methacryloylanthracene |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438842/ https://www.ncbi.nlm.nih.gov/pubmed/26029389 http://dx.doi.org/10.1107/S2056989015004090 |
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