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Crystal structure of 9-methacryloylanthracene

In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methyl­prop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about...

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Autores principales: Agrahari, Aditya, Wagers, Patrick O., Schildcrout, Steven M., Masnovi, John, Youngs, Wiley J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438842/
https://www.ncbi.nlm.nih.gov/pubmed/26029389
http://dx.doi.org/10.1107/S2056989015004090
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author Agrahari, Aditya
Wagers, Patrick O.
Schildcrout, Steven M.
Masnovi, John
Youngs, Wiley J.
author_facet Agrahari, Aditya
Wagers, Patrick O.
Schildcrout, Steven M.
Masnovi, John
Youngs, Wiley J.
author_sort Agrahari, Aditya
collection PubMed
description In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methyl­prop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about the Csp (2)—Csp (2) bond in the side chain is transoid. In the crystal, the end rings of the anthryl units in adjacent mol­ecules associate in parallel–planar orientations [shortest centroid–centroid distance = 3.6320 (7) Å]. A weak hydrogen bond is observed between an aromatic H atom and the O atom of a mol­ecule displaced by translation in the a-axis direction, forming sheets of parallel-planar anthryl groups packing in this direction.
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spelling pubmed-44388422015-05-30 Crystal structure of 9-methacryloylanthracene Agrahari, Aditya Wagers, Patrick O. Schildcrout, Steven M. Masnovi, John Youngs, Wiley J. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(18)H(14)O, with systematic name 1-(anthracen-9-yl)-2-methyl­prop-2-en-1-one, the ketonic C atom lies 0.2030 (16) Å out of the anthryl-ring-system plane. The dihedral angle between the planes of the anthryl and methacryloyl moieties is 88.30 (3)° and the stereochemistry about the Csp (2)—Csp (2) bond in the side chain is transoid. In the crystal, the end rings of the anthryl units in adjacent mol­ecules associate in parallel–planar orientations [shortest centroid–centroid distance = 3.6320 (7) Å]. A weak hydrogen bond is observed between an aromatic H atom and the O atom of a mol­ecule displaced by translation in the a-axis direction, forming sheets of parallel-planar anthryl groups packing in this direction. International Union of Crystallography 2015-03-11 /pmc/articles/PMC4438842/ /pubmed/26029389 http://dx.doi.org/10.1107/S2056989015004090 Text en © Agrahari et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Agrahari, Aditya
Wagers, Patrick O.
Schildcrout, Steven M.
Masnovi, John
Youngs, Wiley J.
Crystal structure of 9-methacryloylanthracene
title Crystal structure of 9-methacryloylanthracene
title_full Crystal structure of 9-methacryloylanthracene
title_fullStr Crystal structure of 9-methacryloylanthracene
title_full_unstemmed Crystal structure of 9-methacryloylanthracene
title_short Crystal structure of 9-methacryloylanthracene
title_sort crystal structure of 9-methacryloylanthracene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438842/
https://www.ncbi.nlm.nih.gov/pubmed/26029389
http://dx.doi.org/10.1107/S2056989015004090
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