Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)

The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent mol­ecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two tri­phenyl­phosphane mol­ecules in a distorted BrNP(2) tetra­hedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent mol­ecules. In the crystal, mol­ecules are linked by weak C—H⋯Br hydrogen bonds and weak C—H⋯π inter­actions into a three-dimensional supra­molecular architecture.