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Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)

The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent mol­ecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two tri­phenyl­phosphane mol­ecules in a distorted BrNP(2) tetra­hedral coord...

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Autores principales: Hockley, Rose, Irshad, Hira, Sheriff, Tippu S., Motevalli, Majid, Marinakis, Sarantos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438846/
https://www.ncbi.nlm.nih.gov/pubmed/26029415
http://dx.doi.org/10.1107/S2056989015004703
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author Hockley, Rose
Irshad, Hira
Sheriff, Tippu S.
Motevalli, Majid
Marinakis, Sarantos
author_facet Hockley, Rose
Irshad, Hira
Sheriff, Tippu S.
Motevalli, Majid
Marinakis, Sarantos
author_sort Hockley, Rose
collection PubMed
description The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent mol­ecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two tri­phenyl­phosphane mol­ecules in a distorted BrNP(2) tetra­hedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent mol­ecules. In the crystal, mol­ecules are linked by weak C—H⋯Br hydrogen bonds and weak C—H⋯π inter­actions into a three-dimensional supra­molecular architecture.
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spelling pubmed-44388462015-05-30 Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II) Hockley, Rose Irshad, Hira Sheriff, Tippu S. Motevalli, Majid Marinakis, Sarantos Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent mol­ecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two tri­phenyl­phosphane mol­ecules in a distorted BrNP(2) tetra­hedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent mol­ecules. In the crystal, mol­ecules are linked by weak C—H⋯Br hydrogen bonds and weak C—H⋯π inter­actions into a three-dimensional supra­molecular architecture. International Union of Crystallography 2015-03-18 /pmc/articles/PMC4438846/ /pubmed/26029415 http://dx.doi.org/10.1107/S2056989015004703 Text en © Hockley et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hockley, Rose
Irshad, Hira
Sheriff, Tippu S.
Motevalli, Majid
Marinakis, Sarantos
Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title_full Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title_fullStr Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title_full_unstemmed Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title_short Crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κP)nickel(II)
title_sort crystal structure of bromido­nitro­syl­bis(tri­phenyl­phosphane-κp)nickel(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438846/
https://www.ncbi.nlm.nih.gov/pubmed/26029415
http://dx.doi.org/10.1107/S2056989015004703
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