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Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II)
The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent molecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two triphenylphosphane molecules in a distorted BrNP(2) tetrahedral coord...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438846/ https://www.ncbi.nlm.nih.gov/pubmed/26029415 http://dx.doi.org/10.1107/S2056989015004703 |
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author | Hockley, Rose Irshad, Hira Sheriff, Tippu S. Motevalli, Majid Marinakis, Sarantos |
author_facet | Hockley, Rose Irshad, Hira Sheriff, Tippu S. Motevalli, Majid Marinakis, Sarantos |
author_sort | Hockley, Rose |
collection | PubMed |
description | The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent molecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two triphenylphosphane molecules in a distorted BrNP(2) tetrahedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent molecules. In the crystal, molecules are linked by weak C—H⋯Br hydrogen bonds and weak C—H⋯π interactions into a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-4438846 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388462015-05-30 Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) Hockley, Rose Irshad, Hira Sheriff, Tippu S. Motevalli, Majid Marinakis, Sarantos Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title complex, [NiBr(NO){P(C(6)H(5))(3)}(2)], comprises two independent molecules each with a similar configuration. The Ni(II) cation is coordinated by one bromide anion, one nitrosyl anion and two triphenylphosphane molecules in a distorted BrNP(2) tetrahedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent molecules. In the crystal, molecules are linked by weak C—H⋯Br hydrogen bonds and weak C—H⋯π interactions into a three-dimensional supramolecular architecture. International Union of Crystallography 2015-03-18 /pmc/articles/PMC4438846/ /pubmed/26029415 http://dx.doi.org/10.1107/S2056989015004703 Text en © Hockley et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Hockley, Rose Irshad, Hira Sheriff, Tippu S. Motevalli, Majid Marinakis, Sarantos Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title | Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title_full | Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title_fullStr | Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title_full_unstemmed | Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title_short | Crystal structure of bromidonitrosylbis(triphenylphosphane-κP)nickel(II) |
title_sort | crystal structure of bromidonitrosylbis(triphenylphosphane-κp)nickel(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438846/ https://www.ncbi.nlm.nih.gov/pubmed/26029415 http://dx.doi.org/10.1107/S2056989015004703 |
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