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Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol

The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the ortho­rhom­bic space group Pna2(1), with two mol­ecules in the asymmetric unit (Z′ = 2). Each mol­ecule consists of a 2-hy­droxy Schiff base moiety linked through a spacer to a 2-amino­benzo­thia­zole moiety. Each mol­ecule contains an int...

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Detalles Bibliográficos
Autores principales: Hijji, Yousef, Barare, Belygona, Wairia, Gilbert, Butcher, Ray J., Wikaira, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/
https://www.ncbi.nlm.nih.gov/pubmed/26029397
http://dx.doi.org/10.1107/S2056989015005228
Descripción
Sumario:The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the ortho­rhom­bic space group Pna2(1), with two mol­ecules in the asymmetric unit (Z′ = 2). Each mol­ecule consists of a 2-hy­droxy Schiff base moiety linked through a spacer to a 2-amino­benzo­thia­zole moiety. Each mol­ecule contains an intra­molecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak inter­molecular C—H⋯N inter­actions. The structure was refined as an inversion twin