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Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol
The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the orthorhombic space group Pna2(1), with two molecules in the asymmetric unit (Z′ = 2). Each molecule consists of a 2-hydroxy Schiff base moiety linked through a spacer to a 2-aminobenzothiazole moiety. Each molecule contains an int...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/ https://www.ncbi.nlm.nih.gov/pubmed/26029397 http://dx.doi.org/10.1107/S2056989015005228 |
Sumario: | The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the orthorhombic space group Pna2(1), with two molecules in the asymmetric unit (Z′ = 2). Each molecule consists of a 2-hydroxy Schiff base moiety linked through a spacer to a 2-aminobenzothiazole moiety. Each molecule contains an intramolecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak intermolecular C—H⋯N interactions. The structure was refined as an inversion twin |
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