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Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol
The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the orthorhombic space group Pna2(1), with two molecules in the asymmetric unit (Z′ = 2). Each molecule consists of a 2-hydroxy Schiff base moiety linked through a spacer to a 2-aminobenzothiazole moiety. Each molecule contains an int...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/ https://www.ncbi.nlm.nih.gov/pubmed/26029397 http://dx.doi.org/10.1107/S2056989015005228 |
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author | Hijji, Yousef Barare, Belygona Wairia, Gilbert Butcher, Ray J. Wikaira, Jan |
author_facet | Hijji, Yousef Barare, Belygona Wairia, Gilbert Butcher, Ray J. Wikaira, Jan |
author_sort | Hijji, Yousef |
collection | PubMed |
description | The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the orthorhombic space group Pna2(1), with two molecules in the asymmetric unit (Z′ = 2). Each molecule consists of a 2-hydroxy Schiff base moiety linked through a spacer to a 2-aminobenzothiazole moiety. Each molecule contains an intramolecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak intermolecular C—H⋯N interactions. The structure was refined as an inversion twin |
format | Online Article Text |
id | pubmed-4438847 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388472015-05-30 Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol Hijji, Yousef Barare, Belygona Wairia, Gilbert Butcher, Ray J. Wikaira, Jan Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the orthorhombic space group Pna2(1), with two molecules in the asymmetric unit (Z′ = 2). Each molecule consists of a 2-hydroxy Schiff base moiety linked through a spacer to a 2-aminobenzothiazole moiety. Each molecule contains an intramolecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak intermolecular C—H⋯N interactions. The structure was refined as an inversion twin International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438847/ /pubmed/26029397 http://dx.doi.org/10.1107/S2056989015005228 Text en © Hijji et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Hijji, Yousef Barare, Belygona Wairia, Gilbert Butcher, Ray J. Wikaira, Jan Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title | Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title_full | Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title_fullStr | Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title_full_unstemmed | Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title_short | Crystal structure of (E)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
title_sort | crystal structure of (e)-2-{[(6-methoxy-1,3-benzothiazol-2-yl)imino]methyl}phenol |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/ https://www.ncbi.nlm.nih.gov/pubmed/26029397 http://dx.doi.org/10.1107/S2056989015005228 |
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