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Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol

The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the ortho­rhom­bic space group Pna2(1), with two mol­ecules in the asymmetric unit (Z′ = 2). Each mol­ecule consists of a 2-hy­droxy Schiff base moiety linked through a spacer to a 2-amino­benzo­thia­zole moiety. Each mol­ecule contains an int...

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Autores principales: Hijji, Yousef, Barare, Belygona, Wairia, Gilbert, Butcher, Ray J., Wikaira, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/
https://www.ncbi.nlm.nih.gov/pubmed/26029397
http://dx.doi.org/10.1107/S2056989015005228
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author Hijji, Yousef
Barare, Belygona
Wairia, Gilbert
Butcher, Ray J.
Wikaira, Jan
author_facet Hijji, Yousef
Barare, Belygona
Wairia, Gilbert
Butcher, Ray J.
Wikaira, Jan
author_sort Hijji, Yousef
collection PubMed
description The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the ortho­rhom­bic space group Pna2(1), with two mol­ecules in the asymmetric unit (Z′ = 2). Each mol­ecule consists of a 2-hy­droxy Schiff base moiety linked through a spacer to a 2-amino­benzo­thia­zole moiety. Each mol­ecule contains an intra­molecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak inter­molecular C—H⋯N inter­actions. The structure was refined as an inversion twin
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spelling pubmed-44388472015-05-30 Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol Hijji, Yousef Barare, Belygona Wairia, Gilbert Butcher, Ray J. Wikaira, Jan Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(15)H(12)N(2)O(2)S, crystallizes in the ortho­rhom­bic space group Pna2(1), with two mol­ecules in the asymmetric unit (Z′ = 2). Each mol­ecule consists of a 2-hy­droxy Schiff base moiety linked through a spacer to a 2-amino­benzo­thia­zole moiety. Each mol­ecule contains an intra­molecular hydrogen bond between the –OH group and imine N atom, forming a six-membered ring. The two independent molecules are linked by a pair of C—H⋯O hydrogen bonds, forming dimers with an R (2) (2)(20) ring motif. These dimers are further lined into sheets in the ab plane by weak inter­molecular C—H⋯N inter­actions. The structure was refined as an inversion twin International Union of Crystallography 2015-03-21 /pmc/articles/PMC4438847/ /pubmed/26029397 http://dx.doi.org/10.1107/S2056989015005228 Text en © Hijji et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Hijji, Yousef
Barare, Belygona
Wairia, Gilbert
Butcher, Ray J.
Wikaira, Jan
Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title_full Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title_fullStr Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title_full_unstemmed Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title_short Crystal structure of (E)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
title_sort crystal structure of (e)-2-{[(6-meth­oxy-1,3-benzo­thia­zol-2-yl)imino]­meth­yl}phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438847/
https://www.ncbi.nlm.nih.gov/pubmed/26029397
http://dx.doi.org/10.1107/S2056989015005228
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