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Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide

The title compound, C(24)H(22)N(4)O(5), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol­ecule = 77.95 (3)°]. The two mol­ecules exhibit similar conformations with an extended structure....

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Detalles Bibliográficos
Autores principales: Shripanavar, Chetan Shrimandhar, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438849/
https://www.ncbi.nlm.nih.gov/pubmed/26029395
http://dx.doi.org/10.1107/S2056989015004569
Descripción
Sumario:The title compound, C(24)H(22)N(4)O(5), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol­ecule = 77.95 (3)°]. The two mol­ecules exhibit similar conformations with an extended structure. An intra­molecular C—H⋯N hydrogen bond occurs in each mol­ecule. The two mol­ecules are linked by a bifurcated N—H⋯(O,N) hydrogen bond involving the NH group in mol­ecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N—H⋯(O,N) hydrogen bonds involving the NH group in mol­ecule B as donor. C—H⋯O inter­actions are also observed.