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Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide
The title compound, C(24)H(22)N(4)O(5), crystallizes with two molecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each molecule = 77.95 (3)°]. The two molecules exhibit similar conformations with an extended structure....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438849/ https://www.ncbi.nlm.nih.gov/pubmed/26029395 http://dx.doi.org/10.1107/S2056989015004569 |
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author | Shripanavar, Chetan Shrimandhar Butcher, Ray J. |
author_facet | Shripanavar, Chetan Shrimandhar Butcher, Ray J. |
author_sort | Shripanavar, Chetan Shrimandhar |
collection | PubMed |
description | The title compound, C(24)H(22)N(4)O(5), crystallizes with two molecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each molecule = 77.95 (3)°]. The two molecules exhibit similar conformations with an extended structure. An intramolecular C—H⋯N hydrogen bond occurs in each molecule. The two molecules are linked by a bifurcated N—H⋯(O,N) hydrogen bond involving the NH group in molecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N—H⋯(O,N) hydrogen bonds involving the NH group in molecule B as donor. C—H⋯O interactions are also observed. |
format | Online Article Text |
id | pubmed-4438849 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44388492015-05-30 Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide Shripanavar, Chetan Shrimandhar Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(24)H(22)N(4)O(5), crystallizes with two molecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each molecule = 77.95 (3)°]. The two molecules exhibit similar conformations with an extended structure. An intramolecular C—H⋯N hydrogen bond occurs in each molecule. The two molecules are linked by a bifurcated N—H⋯(O,N) hydrogen bond involving the NH group in molecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N—H⋯(O,N) hydrogen bonds involving the NH group in molecule B as donor. C—H⋯O interactions are also observed. International Union of Crystallography 2015-03-18 /pmc/articles/PMC4438849/ /pubmed/26029395 http://dx.doi.org/10.1107/S2056989015004569 Text en © Shripanavar and Butcher 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shripanavar, Chetan Shrimandhar Butcher, Ray J. Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title | Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title_full | Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title_fullStr | Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title_full_unstemmed | Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title_short | Crystal structure of (2E)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-N′-(4-nitrobenzylidene)ethanohydrazide |
title_sort | crystal structure of (2e)-2-methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}-n′-(4-nitrobenzylidene)ethanohydrazide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438849/ https://www.ncbi.nlm.nih.gov/pubmed/26029395 http://dx.doi.org/10.1107/S2056989015004569 |
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