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Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide

The title compound, C(24)H(22)N(4)O(5), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol­ecule = 77.95 (3)°]. The two mol­ecules exhibit similar conformations with an extended structure....

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Detalles Bibliográficos
Autores principales: Shripanavar, Chetan Shrimandhar, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438849/
https://www.ncbi.nlm.nih.gov/pubmed/26029395
http://dx.doi.org/10.1107/S2056989015004569
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author Shripanavar, Chetan Shrimandhar
Butcher, Ray J.
author_facet Shripanavar, Chetan Shrimandhar
Butcher, Ray J.
author_sort Shripanavar, Chetan Shrimandhar
collection PubMed
description The title compound, C(24)H(22)N(4)O(5), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol­ecule = 77.95 (3)°]. The two mol­ecules exhibit similar conformations with an extended structure. An intra­molecular C—H⋯N hydrogen bond occurs in each mol­ecule. The two mol­ecules are linked by a bifurcated N—H⋯(O,N) hydrogen bond involving the NH group in mol­ecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N—H⋯(O,N) hydrogen bonds involving the NH group in mol­ecule B as donor. C—H⋯O inter­actions are also observed.
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spelling pubmed-44388492015-05-30 Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide Shripanavar, Chetan Shrimandhar Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(24)H(22)N(4)O(5), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol­ecule = 77.95 (3)°]. The two mol­ecules exhibit similar conformations with an extended structure. An intra­molecular C—H⋯N hydrogen bond occurs in each mol­ecule. The two mol­ecules are linked by a bifurcated N—H⋯(O,N) hydrogen bond involving the NH group in mol­ecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N—H⋯(O,N) hydrogen bonds involving the NH group in mol­ecule B as donor. C—H⋯O inter­actions are also observed. International Union of Crystallography 2015-03-18 /pmc/articles/PMC4438849/ /pubmed/26029395 http://dx.doi.org/10.1107/S2056989015004569 Text en © Shripanavar and Butcher 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shripanavar, Chetan Shrimandhar
Butcher, Ray J.
Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title_full Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title_fullStr Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title_full_unstemmed Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title_short Crystal structure of (2E)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-N′-(4-nitro­benzyl­idene)ethano­hydrazide
title_sort crystal structure of (2e)-2-meth­oxy­imino-2-{2-[(2-methyl­phen­oxy)meth­yl]phen­yl}-n′-(4-nitro­benzyl­idene)ethano­hydrazide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438849/
https://www.ncbi.nlm.nih.gov/pubmed/26029395
http://dx.doi.org/10.1107/S2056989015004569
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