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Crystal structures of the water and acetone monosolvates of bis­[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]­manganese(II) bis­(hexa­fluorido­phosphate)

The crystal structures of bis­[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]­man­gan­ese(II) bis­(hexa­fluorido­phosphate) monohydrate, [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·H(2)O, (1), and bis­[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]­manganese(II) bis(hexa­fluorido­phosphate) acetone monosolvate, (2),...

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Detalles Bibliográficos
Autores principales: Lourenço, Leandro M. O., Almeida Paz, Filipe A., Fernandes, José A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438851/
https://www.ncbi.nlm.nih.gov/pubmed/26029382
http://dx.doi.org/10.1107/S2056989015003503
Descripción
Sumario:The crystal structures of bis­[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]­man­gan­ese(II) bis­(hexa­fluorido­phosphate) monohydrate, [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·H(2)O, (1), and bis­[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]­manganese(II) bis(hexa­fluorido­phosphate) acetone monosolvate, (2), [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·CH(3)COCH(3), are described. At 150 K, (1) and (2) have monoclinic (P2(1)/c) and ortho­rhom­bic (C222(1)) symmetries, respectively. Both structures exhibit octahedrally coordinated Mn(II) atoms and disorder. They display weak inter­actions, such as C—H⋯F, C—H⋯N, C—H⋯π, F⋯π and π–π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal.