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Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·H(2)O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) acetone monosolvate, (2),...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438851/ https://www.ncbi.nlm.nih.gov/pubmed/26029382 http://dx.doi.org/10.1107/S2056989015003503 |
Sumario: | The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·H(2)O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C(20)H(14)N(4))(2)](PF(6))(2)·CH(3)COCH(3), are described. At 150 K, (1) and (2) have monoclinic (P2(1)/c) and orthorhombic (C222(1)) symmetries, respectively. Both structures exhibit octahedrally coordinated Mn(II) atoms and disorder. They display weak interactions, such as C—H⋯F, C—H⋯N, C—H⋯π, F⋯π and π–π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal. |
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