Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate

The complete mol­ecule of the title compound, C(26)H(30)N(4)O(4), is generated by crystallographic inversion symmetry. The dihedral angle between the planes of the benzene and pyrrole rings is 45.20 (11)°; the N atom bonded to the the benzene ring and the pyrrole N atom are in a syn conformation. Th...

Descripción completa

Detalles Bibliográficos
Autores principales: Alshawi, Jasim, Yousif, Muoayed, Timco, Gregore, Vitorica Yrezabal, Inigo J., Winpenny, Richard, Al-Jeboori, Mohamad J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438852/
https://www.ncbi.nlm.nih.gov/pubmed/26029445
http://dx.doi.org/10.1107/S2056989015005113
_version_ 1782372403864666112
author Alshawi, Jasim
Yousif, Muoayed
Timco, Gregore
Vitorica Yrezabal, Inigo J.
Winpenny, Richard
Al-Jeboori, Mohamad J.
author_facet Alshawi, Jasim
Yousif, Muoayed
Timco, Gregore
Vitorica Yrezabal, Inigo J.
Winpenny, Richard
Al-Jeboori, Mohamad J.
author_sort Alshawi, Jasim
collection PubMed
description The complete mol­ecule of the title compound, C(26)H(30)N(4)O(4), is generated by crystallographic inversion symmetry. The dihedral angle between the planes of the benzene and pyrrole rings is 45.20 (11)°; the N atom bonded to the the benzene ring and the pyrrole N atom are in a syn conformation. The side chain adopts an extended conformation [N—C—C—C = 169.07 (17)° and C—O—C—C = −176.54 (17)°]. No directional inter­actions could be identified in the crystal packing.
format Online
Article
Text
id pubmed-4438852
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44388522015-05-30 Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate Alshawi, Jasim Yousif, Muoayed Timco, Gregore Vitorica Yrezabal, Inigo J. Winpenny, Richard Al-Jeboori, Mohamad J. Acta Crystallogr E Crystallogr Commun Data Reports The complete mol­ecule of the title compound, C(26)H(30)N(4)O(4), is generated by crystallographic inversion symmetry. The dihedral angle between the planes of the benzene and pyrrole rings is 45.20 (11)°; the N atom bonded to the the benzene ring and the pyrrole N atom are in a syn conformation. The side chain adopts an extended conformation [N—C—C—C = 169.07 (17)° and C—O—C—C = −176.54 (17)°]. No directional inter­actions could be identified in the crystal packing. International Union of Crystallography 2015-03-25 /pmc/articles/PMC4438852/ /pubmed/26029445 http://dx.doi.org/10.1107/S2056989015005113 Text en © Alshawi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Alshawi, Jasim
Yousif, Muoayed
Timco, Gregore
Vitorica Yrezabal, Inigo J.
Winpenny, Richard
Al-Jeboori, Mohamad J.
Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title_full Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title_fullStr Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title_full_unstemmed Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title_short Crystal structure of diethyl 3,3′-{2,2′-(1E)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1H-pyrrole-2,1-di­yl)}di­propano­ate
title_sort crystal structure of diethyl 3,3′-{2,2′-(1e)-[1,4-phenyl­enebis(azan-1-yl-1-yl­idene)]bis­(methan-1-yl-1-yl­idene)bis­(1h-pyrrole-2,1-di­yl)}di­propano­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438852/
https://www.ncbi.nlm.nih.gov/pubmed/26029445
http://dx.doi.org/10.1107/S2056989015005113
work_keys_str_mv AT alshawijasim crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate
AT yousifmuoayed crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate
AT timcogregore crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate
AT vitoricayrezabalinigoj crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate
AT winpennyrichard crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate
AT aljeboorimohamadj crystalstructureofdiethyl33221e14phenylenebisazan1yl1ylidenebismethan1yl1ylidenebis1hpyrrole21diyldipropanoate

Ejemplares similares