Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine

In the title compound, C(25)H(20)ClN(3)O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In th...

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Autores principales: Thirumurthy, Kannan, Thirunarayanan, Ganesamoorthy, Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438854/
https://www.ncbi.nlm.nih.gov/pubmed/26029405
http://dx.doi.org/10.1107/S2056989015005794
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author Thirumurthy, Kannan
Thirunarayanan, Ganesamoorthy
Murugavel, S.
author_facet Thirumurthy, Kannan
Thirunarayanan, Ganesamoorthy
Murugavel, S.
author_sort Thirumurthy, Kannan
collection PubMed
description In the title compound, C(25)H(20)ClN(3)O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, mol­ecules are linked by C—H⋯π and π—π inter­actions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supra­molecular network.
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spelling pubmed-44388542015-05-30 Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine Thirumurthy, Kannan Thirunarayanan, Ganesamoorthy Murugavel, S. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(25)H(20)ClN(3)O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, mol­ecules are linked by C—H⋯π and π—π inter­actions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supra­molecular network. International Union of Crystallography 2015-03-28 /pmc/articles/PMC4438854/ /pubmed/26029405 http://dx.doi.org/10.1107/S2056989015005794 Text en © Thirumurthy et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Thirumurthy, Kannan
Thirunarayanan, Ganesamoorthy
Murugavel, S.
Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title_full Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title_fullStr Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title_full_unstemmed Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title_short Crystal structure of (E)-N-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9H-carbazol-3-amine
title_sort crystal structure of (e)-n-[(2-chloro-6-meth­oxy­quinolin-3-yl)methyl­idene]-9-ethyl-9h-carbazol-3-amine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438854/
https://www.ncbi.nlm.nih.gov/pubmed/26029405
http://dx.doi.org/10.1107/S2056989015005794
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AT murugavels crystalstructureofen2chloro6methoxyquinolin3ylmethylidene9ethyl9hcarbazol3amine

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