Crystal structure of 3-mesityl-1-[(pyridin-2-yl)meth­yl]-3,4,5,6-tetra­hydro­pyrim­idin-1-ium bromide monohydrate

In the title hydrated salt, C(19)H(24)N(3) (+)·Br(−)·H(2)O, the values of the N—C bond lengths within the tetra­hydro­pyrimidinium ring indicate delocalization of the N=C double bond. In the cation, the dihedral angle formed by the pyridine and benzene rings is 14.97 (12)°. In the crystal, ions and...

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Detalles Bibliográficos
Autores principales: Quo, Qi, Yang, Liangru, Mao, Pu, Xiao, Yongmei, Yuan, Jinwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438856/
https://www.ncbi.nlm.nih.gov/pubmed/26029425
http://dx.doi.org/10.1107/S2056989015003989
Descripción
Sumario:In the title hydrated salt, C(19)H(24)N(3) (+)·Br(−)·H(2)O, the values of the N—C bond lengths within the tetra­hydro­pyrimidinium ring indicate delocalization of the N=C double bond. In the cation, the dihedral angle formed by the pyridine and benzene rings is 14.97 (12)°. In the crystal, ions and water mol­ecules are linked by O—H⋯Br, O—H⋯N, C—H⋯Br and C—H⋯O hydrogen bonds into chains running parallel to the b axis.

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