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Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph

The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthes...

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Autores principales: Veeramani, Vediyappan, Madhu, Rajesh, Chen, Shen-Ming, Lou, Bih-Show, Palanisamy, Jayabal, Vasantha, Vairathevar Sivasamy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4441114/
https://www.ncbi.nlm.nih.gov/pubmed/25998156
http://dx.doi.org/10.1038/srep10141
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author Veeramani, Vediyappan
Madhu, Rajesh
Chen, Shen-Ming
Lou, Bih-Show
Palanisamy, Jayabal
Vasantha, Vairathevar Sivasamy
author_facet Veeramani, Vediyappan
Madhu, Rajesh
Chen, Shen-Ming
Lou, Bih-Show
Palanisamy, Jayabal
Vasantha, Vairathevar Sivasamy
author_sort Veeramani, Vediyappan
collection PubMed
description The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures.
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spelling pubmed-44411142015-05-29 Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph Veeramani, Vediyappan Madhu, Rajesh Chen, Shen-Ming Lou, Bih-Show Palanisamy, Jayabal Vasantha, Vairathevar Sivasamy Sci Rep Article The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures. Nature Publishing Group 2015-05-22 /pmc/articles/PMC4441114/ /pubmed/25998156 http://dx.doi.org/10.1038/srep10141 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Veeramani, Vediyappan
Madhu, Rajesh
Chen, Shen-Ming
Lou, Bih-Show
Palanisamy, Jayabal
Vasantha, Vairathevar Sivasamy
Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title_full Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title_fullStr Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title_full_unstemmed Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title_short Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
title_sort biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4441114/
https://www.ncbi.nlm.nih.gov/pubmed/25998156
http://dx.doi.org/10.1038/srep10141
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