Cargando…
Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph
The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthes...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4441114/ https://www.ncbi.nlm.nih.gov/pubmed/25998156 http://dx.doi.org/10.1038/srep10141 |
_version_ | 1782372740650500096 |
---|---|
author | Veeramani, Vediyappan Madhu, Rajesh Chen, Shen-Ming Lou, Bih-Show Palanisamy, Jayabal Vasantha, Vairathevar Sivasamy |
author_facet | Veeramani, Vediyappan Madhu, Rajesh Chen, Shen-Ming Lou, Bih-Show Palanisamy, Jayabal Vasantha, Vairathevar Sivasamy |
author_sort | Veeramani, Vediyappan |
collection | PubMed |
description | The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures. |
format | Online Article Text |
id | pubmed-4441114 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | Nature Publishing Group |
record_format | MEDLINE/PubMed |
spelling | pubmed-44411142015-05-29 Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph Veeramani, Vediyappan Madhu, Rajesh Chen, Shen-Ming Lou, Bih-Show Palanisamy, Jayabal Vasantha, Vairathevar Sivasamy Sci Rep Article The biomass-derived activated carbons (ACs) have been prepared with high surface areas up to 793 m(2) g(−1) is by ZnCl(2) activation at three different temperatures, viz. AC700, AC800, and AC900. The AC samples were characterized by a variety of analytical and spectroscopy techniques. The as-synthesized ACs were adopted for the simultaneous electrochemical detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). For comparison, reduced graphene oxide (RGO) was employed for the proposed sensor. The high surface area, modulated pore size and the presence of oxygen surface functional groups like heteroatoms (83.427% C, 1.085% N, 0.383% S, and 0.861% H) in the biomass-derived AC is found to be responsible for the excellent catalytic activities of biomolecules. Fascinatingly, the facile sensor further used to detect biomolecules levels in the snail hemolymph and human blood serum. Notably, the obtained analytical parameters for the biomolecules detection over the AC modified GCE, outperforming several carbon-based modified electrodes in literatures. Nature Publishing Group 2015-05-22 /pmc/articles/PMC4441114/ /pubmed/25998156 http://dx.doi.org/10.1038/srep10141 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Article Veeramani, Vediyappan Madhu, Rajesh Chen, Shen-Ming Lou, Bih-Show Palanisamy, Jayabal Vasantha, Vairathevar Sivasamy Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title | Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title_full | Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title_fullStr | Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title_full_unstemmed | Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title_short | Biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
title_sort | biomass-derived functional porous carbons as novel electrode material for the practical detection of biomolecules in human serum and snail hemolymph |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4441114/ https://www.ncbi.nlm.nih.gov/pubmed/25998156 http://dx.doi.org/10.1038/srep10141 |
work_keys_str_mv | AT veeramanivediyappan biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph AT madhurajesh biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph AT chenshenming biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph AT loubihshow biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph AT palanisamyjayabal biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph AT vasanthavairathevarsivasamy biomassderivedfunctionalporouscarbonsasnovelelectrodematerialforthepracticaldetectionofbiomoleculesinhumanserumandsnailhemolymph |