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Million-Fold Electrical Conductivity Enhancement in Fe(2)(DEBDC) versus Mn(2)(DEBDC) (E = S, O)
[Image: see text] Reaction of FeCl(2) and H(4)DSBDC (2,5-disulfhydrylbenzene-1,4-dicarboxylic acid) leads to the formation of Fe(2)(DSBDC), an analogue of M(2)(DOBDC) (MOF-74, DOBDC(4–) = 2,5-dihydroxybenzene-1,4-dicarboxylate). The bulk electrical conductivity values of both Fe(2)(DSBDC) and Fe(2)(...
Autores principales: | Sun, Lei, Hendon, Christopher H., Minier, Mikael A., Walsh, Aron, Dincă, Mircea |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2015
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4442594/ https://www.ncbi.nlm.nih.gov/pubmed/25932955 http://dx.doi.org/10.1021/jacs.5b02897 |
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