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Mechanistic Significance of the Si–O–Pd Bond in the Palladium-Catalyzed Cross-Coupling Reactions of Arylsilanolates

[Image: see text] Through the combination of reaction kinetics (both stoichiometric and catalytic), solution- and solid-state characterization of arylpalladium(II) arylsilanolates, and computational analysis, the intermediacy of covalent adducts containing Si–O–Pd linkages in the cross-coupling reac...

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Detalles Bibliográficos
Autores principales:	Tymonko, Steven A., Smith, Russell C., Ambrosi, Andrea, Ober, Michael H., Wang, Hao, Denmark, Scott E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2015
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4442671/ https://www.ncbi.nlm.nih.gov/pubmed/25945516 http://dx.doi.org/10.1021/jacs.5b02518

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