Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide

In the title compound, C(9)H(7)FN(4)OS, the mol­ecules are almost planar, with an r.m.s. deviation of 0.047 (3) Å from the mean plane defined by the non-H atoms and a maximum deviation of 0.123 (2) Å for the amine N atom. The torsion angle for the N—N—C—S unit is 176.57 (19)°. In the crystal, mol­ec...

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Autores principales: Bittencourt, Viviane C. D., Almeida, Vitor Y. G., Back, Davi F., Gervini, Vanessa C., de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459295/
https://www.ncbi.nlm.nih.gov/pubmed/26090179
http://dx.doi.org/10.1107/S2056989015008609
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author Bittencourt, Viviane C. D.
Almeida, Vitor Y. G.
Back, Davi F.
Gervini, Vanessa C.
de Oliveira, Adriano Bof
author_facet Bittencourt, Viviane C. D.
Almeida, Vitor Y. G.
Back, Davi F.
Gervini, Vanessa C.
de Oliveira, Adriano Bof
author_sort Bittencourt, Viviane C. D.
collection PubMed
description In the title compound, C(9)H(7)FN(4)OS, the mol­ecules are almost planar, with an r.m.s. deviation of 0.047 (3) Å from the mean plane defined by the non-H atoms and a maximum deviation of 0.123 (2) Å for the amine N atom. The torsion angle for the N—N—C—S unit is 176.57 (19)°. In the crystal, mol­ecules are linked into inversion dimers via pairs of N—H⋯F hydrogen bonds and, additionally, through N—H⋯O and N—H⋯S hydrogen bonds, building a two-dimensional hydrogen-bond network parallel to the (103) plane. An intra­molecular N—H⋯O inter­action is also observed.
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spelling pubmed-44592952015-06-18 Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide Bittencourt, Viviane C. D. Almeida, Vitor Y. G. Back, Davi F. Gervini, Vanessa C. de Oliveira, Adriano Bof Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(9)H(7)FN(4)OS, the mol­ecules are almost planar, with an r.m.s. deviation of 0.047 (3) Å from the mean plane defined by the non-H atoms and a maximum deviation of 0.123 (2) Å for the amine N atom. The torsion angle for the N—N—C—S unit is 176.57 (19)°. In the crystal, mol­ecules are linked into inversion dimers via pairs of N—H⋯F hydrogen bonds and, additionally, through N—H⋯O and N—H⋯S hydrogen bonds, building a two-dimensional hydrogen-bond network parallel to the (103) plane. An intra­molecular N—H⋯O inter­action is also observed. International Union of Crystallography 2015-05-09 /pmc/articles/PMC4459295/ /pubmed/26090179 http://dx.doi.org/10.1107/S2056989015008609 Text en © Bittencourt et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bittencourt, Viviane C. D.
Almeida, Vitor Y. G.
Back, Davi F.
Gervini, Vanessa C.
de Oliveira, Adriano Bof
Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_full Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_fullStr Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_short Crystal structure of (Z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_sort crystal structure of (z)-2-(5-fluoro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459295/
https://www.ncbi.nlm.nih.gov/pubmed/26090179
http://dx.doi.org/10.1107/S2056989015008609
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