Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide

In the title compound, C(13)H(9)N(3)O(5), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0442 Å] forms dihedral angles of 71.76 (6) and 24.29 (10)° with the C-bonded and N-bonded benzene rings, respectively. In the crystal, mol­ecules are linked by...

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Autores principales: Moreno-Fuquen, Rodolfo, Azcárate, Alexis, Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459296/
https://www.ncbi.nlm.nih.gov/pubmed/26090182
http://dx.doi.org/10.1107/S2056989015008695
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author Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_facet Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description In the title compound, C(13)H(9)N(3)O(5), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0442 Å] forms dihedral angles of 71.76 (6) and 24.29 (10)° with the C-bonded and N-bonded benzene rings, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds forming C(4) chains along [100]. Weak C—H⋯O contacts link the mol­ecules into (100) sheets containing edge-fused R (4) (4)(30) rings. Together, the N—H⋯O and C—H⋯O hydrogen bonds generate a three-dimensional network.
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spelling pubmed-44592962015-06-18 Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide Moreno-Fuquen, Rodolfo Azcárate, Alexis Kennedy, Alan R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(13)H(9)N(3)O(5), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0442 Å] forms dihedral angles of 71.76 (6) and 24.29 (10)° with the C-bonded and N-bonded benzene rings, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds forming C(4) chains along [100]. Weak C—H⋯O contacts link the mol­ecules into (100) sheets containing edge-fused R (4) (4)(30) rings. Together, the N—H⋯O and C—H⋯O hydrogen bonds generate a three-dimensional network. International Union of Crystallography 2015-05-09 /pmc/articles/PMC4459296/ /pubmed/26090182 http://dx.doi.org/10.1107/S2056989015008695 Text en © Moreno-Fuquen et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title_full Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title_fullStr Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title_full_unstemmed Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title_short Crystal structure of 2-nitro-N-(2-nitro­phen­yl)benzamide
title_sort crystal structure of 2-nitro-n-(2-nitro­phen­yl)benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459296/
https://www.ncbi.nlm.nih.gov/pubmed/26090182
http://dx.doi.org/10.1107/S2056989015008695
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