Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol

The title compound, C(11)H(8)N(2)O(3)S, is roughly planar; the di­hedral angle between the planes of the thio­phene and benzene rings is 8.38 (10)°. An intra­molecular O—H⋯N hydrogen bond generates an S(5) ring motif. In the crystal, mol­ecules are linked into centrosymmetric dimers by pairs of O—H⋯...

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Autores principales: Koçak, Figen, Tanak, Hasan, Ağar, Erbil, Doğan, Onur Erman, Özdemir, Namık
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459297/
https://www.ncbi.nlm.nih.gov/pubmed/26090201
http://dx.doi.org/10.1107/S2056989015009202
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author Koçak, Figen
Tanak, Hasan
Ağar, Erbil
Doğan, Onur Erman
Özdemir, Namık
author_facet Koçak, Figen
Tanak, Hasan
Ağar, Erbil
Doğan, Onur Erman
Özdemir, Namık
author_sort Koçak, Figen
collection PubMed
description The title compound, C(11)H(8)N(2)O(3)S, is roughly planar; the di­hedral angle between the planes of the thio­phene and benzene rings is 8.38 (10)°. An intra­molecular O—H⋯N hydrogen bond generates an S(5) ring motif. In the crystal, mol­ecules are linked into centrosymmetric dimers by pairs of O—H⋯O hydrogen bonds with an R (2) (2)(22) graph-set motif. Aromatic π–π stacking inter­actions [centroid–centroid sep­ar­ations = 3.653 (3) and 3.852 (3) Å] link the dimers into a three-dimensional network.
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spelling pubmed-44592972015-06-18 Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol Koçak, Figen Tanak, Hasan Ağar, Erbil Doğan, Onur Erman Özdemir, Namık Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(11)H(8)N(2)O(3)S, is roughly planar; the di­hedral angle between the planes of the thio­phene and benzene rings is 8.38 (10)°. An intra­molecular O—H⋯N hydrogen bond generates an S(5) ring motif. In the crystal, mol­ecules are linked into centrosymmetric dimers by pairs of O—H⋯O hydrogen bonds with an R (2) (2)(22) graph-set motif. Aromatic π–π stacking inter­actions [centroid–centroid sep­ar­ations = 3.653 (3) and 3.852 (3) Å] link the dimers into a three-dimensional network. International Union of Crystallography 2015-05-23 /pmc/articles/PMC4459297/ /pubmed/26090201 http://dx.doi.org/10.1107/S2056989015009202 Text en © Koçak et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Koçak, Figen
Tanak, Hasan
Ağar, Erbil
Doğan, Onur Erman
Özdemir, Namık
Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title_full Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title_fullStr Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title_full_unstemmed Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title_short Crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
title_sort crystal structure of 2-{[(5-nitro­thio­phen-2-yl)methyl­idene]amino}­phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459297/
https://www.ncbi.nlm.nih.gov/pubmed/26090201
http://dx.doi.org/10.1107/S2056989015009202
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