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Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid

In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. A short intra­molecular C—H⋯O contact is also seen. In the crystal, carb­oxy­lic acid inversion dimers linked by pair...

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Detalles Bibliográficos
Autores principales: Shahid, Muhammad, Choudhary, Muhammad Aziz, Butt, Arshad Farooq, Tahir, Muhammad Nawaz, Salim, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459298/
https://www.ncbi.nlm.nih.gov/pubmed/26090194
http://dx.doi.org/10.1107/S2056989015009032
Descripción
Sumario:In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. A short intra­molecular C—H⋯O contact is also seen. In the crystal, carb­oxy­lic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Conversely, the N—H group does not form a hydrogen bond. Aromatic π–π inter­actions exist at a centroid–centroid distance of 3.8423 (15) Å between the benzene rings. An extremely weak C—H⋯π inter­action also is present.