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Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid

In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. A short intra­molecular C—H⋯O contact is also seen. In the crystal, carb­oxy­lic acid inversion dimers linked by pair...

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Autores principales: Shahid, Muhammad, Choudhary, Muhammad Aziz, Butt, Arshad Farooq, Tahir, Muhammad Nawaz, Salim, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459298/
https://www.ncbi.nlm.nih.gov/pubmed/26090194
http://dx.doi.org/10.1107/S2056989015009032
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author Shahid, Muhammad
Choudhary, Muhammad Aziz
Butt, Arshad Farooq
Tahir, Muhammad Nawaz
Salim, Muhammad
author_facet Shahid, Muhammad
Choudhary, Muhammad Aziz
Butt, Arshad Farooq
Tahir, Muhammad Nawaz
Salim, Muhammad
author_sort Shahid, Muhammad
collection PubMed
description In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. A short intra­molecular C—H⋯O contact is also seen. In the crystal, carb­oxy­lic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Conversely, the N—H group does not form a hydrogen bond. Aromatic π–π inter­actions exist at a centroid–centroid distance of 3.8423 (15) Å between the benzene rings. An extremely weak C—H⋯π inter­action also is present.
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spelling pubmed-44592982015-06-18 Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid Shahid, Muhammad Choudhary, Muhammad Aziz Butt, Arshad Farooq Tahir, Muhammad Nawaz Salim, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. A short intra­molecular C—H⋯O contact is also seen. In the crystal, carb­oxy­lic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Conversely, the N—H group does not form a hydrogen bond. Aromatic π–π inter­actions exist at a centroid–centroid distance of 3.8423 (15) Å between the benzene rings. An extremely weak C—H⋯π inter­action also is present. International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459298/ /pubmed/26090194 http://dx.doi.org/10.1107/S2056989015009032 Text en © Shahid et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shahid, Muhammad
Choudhary, Muhammad Aziz
Butt, Arshad Farooq
Tahir, Muhammad Nawaz
Salim, Muhammad
Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title_full Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title_fullStr Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title_full_unstemmed Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title_short Crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
title_sort crystal structure of 4-benzamido-2-hy­droxy­benzoic acid
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459298/
https://www.ncbi.nlm.nih.gov/pubmed/26090194
http://dx.doi.org/10.1107/S2056989015009032
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