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Crystal structure of 4-benzamido-2-hydroxybenzoic acid
In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intramolecular O—H⋯O hydrogen bond closes an S(6) ring. A short intramolecular C—H⋯O contact is also seen. In the crystal, carboxylic acid inversion dimers linked by pair...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459298/ https://www.ncbi.nlm.nih.gov/pubmed/26090194 http://dx.doi.org/10.1107/S2056989015009032 |
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author | Shahid, Muhammad Choudhary, Muhammad Aziz Butt, Arshad Farooq Tahir, Muhammad Nawaz Salim, Muhammad |
author_facet | Shahid, Muhammad Choudhary, Muhammad Aziz Butt, Arshad Farooq Tahir, Muhammad Nawaz Salim, Muhammad |
author_sort | Shahid, Muhammad |
collection | PubMed |
description | In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intramolecular O—H⋯O hydrogen bond closes an S(6) ring. A short intramolecular C—H⋯O contact is also seen. In the crystal, carboxylic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Conversely, the N—H group does not form a hydrogen bond. Aromatic π–π interactions exist at a centroid–centroid distance of 3.8423 (15) Å between the benzene rings. An extremely weak C—H⋯π interaction also is present. |
format | Online Article Text |
id | pubmed-4459298 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44592982015-06-18 Crystal structure of 4-benzamido-2-hydroxybenzoic acid Shahid, Muhammad Choudhary, Muhammad Aziz Butt, Arshad Farooq Tahir, Muhammad Nawaz Salim, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(14)H(11)NO(4), the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intramolecular O—H⋯O hydrogen bond closes an S(6) ring. A short intramolecular C—H⋯O contact is also seen. In the crystal, carboxylic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Conversely, the N—H group does not form a hydrogen bond. Aromatic π–π interactions exist at a centroid–centroid distance of 3.8423 (15) Å between the benzene rings. An extremely weak C—H⋯π interaction also is present. International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459298/ /pubmed/26090194 http://dx.doi.org/10.1107/S2056989015009032 Text en © Shahid et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Shahid, Muhammad Choudhary, Muhammad Aziz Butt, Arshad Farooq Tahir, Muhammad Nawaz Salim, Muhammad Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title | Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title_full | Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title_fullStr | Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title_full_unstemmed | Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title_short | Crystal structure of 4-benzamido-2-hydroxybenzoic acid |
title_sort | crystal structure of 4-benzamido-2-hydroxybenzoic acid |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459298/ https://www.ncbi.nlm.nih.gov/pubmed/26090194 http://dx.doi.org/10.1107/S2056989015009032 |
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