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Crystal structure of N-carbamo­thioyl-2-methyl­benzamide

There are two mol­ecules in the asymmetric unit of the title compound, C(9)H(10)N(2)OS. In one, the dihedral angle between the aromatic ring and the carbamo­thioyl group is 52.31 (7)° and in the other it is 36.16 (6)°. Each mol­ecule features an intra­molecular N—H⋯O hydrogen bond, which generates a...

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Detalles Bibliográficos
Autores principales: Adam, Farook, Ameram, Nadiah, Tan, Wai Mun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459304/
https://www.ncbi.nlm.nih.gov/pubmed/26090205
http://dx.doi.org/10.1107/S2056989015009585
Descripción
Sumario:There are two mol­ecules in the asymmetric unit of the title compound, C(9)H(10)N(2)OS. In one, the dihedral angle between the aromatic ring and the carbamo­thioyl group is 52.31 (7)° and in the other it is 36.16 (6)°. Each mol­ecule features an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring and the O and S atoms have an anti disposition. In the crystal, mol­ecules are linked by N—H⋯S and N—H⋯O hydrogen bonds, generating separate [130] and [1-30] infinite chains. Weak C—H⋯O and C—H⋯S inter­actions are also observed.