Crystal structure of N-carbamo­thioyl-2-methyl­benzamide

There are two mol­ecules in the asymmetric unit of the title compound, C(9)H(10)N(2)OS. In one, the dihedral angle between the aromatic ring and the carbamo­thioyl group is 52.31 (7)° and in the other it is 36.16 (6)°. Each mol­ecule features an intra­molecular N—H⋯O hydrogen bond, which generates a...

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Detalles Bibliográficos
Autores principales: Adam, Farook, Ameram, Nadiah, Tan, Wai Mun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459304/
https://www.ncbi.nlm.nih.gov/pubmed/26090205
http://dx.doi.org/10.1107/S2056989015009585
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author Adam, Farook
Ameram, Nadiah
Tan, Wai Mun
author_facet Adam, Farook
Ameram, Nadiah
Tan, Wai Mun
author_sort Adam, Farook
collection PubMed
description There are two mol­ecules in the asymmetric unit of the title compound, C(9)H(10)N(2)OS. In one, the dihedral angle between the aromatic ring and the carbamo­thioyl group is 52.31 (7)° and in the other it is 36.16 (6)°. Each mol­ecule features an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring and the O and S atoms have an anti disposition. In the crystal, mol­ecules are linked by N—H⋯S and N—H⋯O hydrogen bonds, generating separate [130] and [1-30] infinite chains. Weak C—H⋯O and C—H⋯S inter­actions are also observed.
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spelling pubmed-44593042015-06-18 Crystal structure of N-carbamo­thioyl-2-methyl­benzamide Adam, Farook Ameram, Nadiah Tan, Wai Mun Acta Crystallogr E Crystallogr Commun Data Reports There are two mol­ecules in the asymmetric unit of the title compound, C(9)H(10)N(2)OS. In one, the dihedral angle between the aromatic ring and the carbamo­thioyl group is 52.31 (7)° and in the other it is 36.16 (6)°. Each mol­ecule features an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring and the O and S atoms have an anti disposition. In the crystal, mol­ecules are linked by N—H⋯S and N—H⋯O hydrogen bonds, generating separate [130] and [1-30] infinite chains. Weak C—H⋯O and C—H⋯S inter­actions are also observed. International Union of Crystallography 2015-05-28 /pmc/articles/PMC4459304/ /pubmed/26090205 http://dx.doi.org/10.1107/S2056989015009585 Text en © Adam et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Adam, Farook
Ameram, Nadiah
Tan, Wai Mun
Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title_full Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title_fullStr Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title_full_unstemmed Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title_short Crystal structure of N-carbamo­thioyl-2-methyl­benzamide
title_sort crystal structure of n-carbamo­thioyl-2-methyl­benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459304/
https://www.ncbi.nlm.nih.gov/pubmed/26090205
http://dx.doi.org/10.1107/S2056989015009585
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