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Crystal structure of 3-(3,4-dimethylanilino)-2-benzofuran-1(3H)-one
In the title compound, C(16)H(15)NO(2), the 2-benzofuran-1(3H)-one and 3,4-dimethylaniline fragments are oriented with a dihedral angle of 89.12 (5)°. N—H⋯O hydrogen-bond interactions join molecules into C(6) chains propagating along the a axis. In addition, there are π–π stacking interactions...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459309/ https://www.ncbi.nlm.nih.gov/pubmed/26090197 http://dx.doi.org/10.1107/S2056989015009299 |
Sumario: | In the title compound, C(16)H(15)NO(2), the 2-benzofuran-1(3H)-one and 3,4-dimethylaniline fragments are oriented with a dihedral angle of 89.12 (5)°. N—H⋯O hydrogen-bond interactions join molecules into C(6) chains propagating along the a axis. In addition, there are π–π stacking interactions between the 2-benzofuranone benzene rings [centroid–centroid distance = 3.7870 (13) Å] and C—H⋯π interactions between one of the methyl groups and the 3,4-dimethylaniline benzene ring. |
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