Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride

The crystal structure of the title compound, [YbCl(2)(H(2)O)(6)]Cl, was determined at 110 K. Samples were obtained from evaporated aceto­nitrile solutions containing the title compound, which consists of a [YbCl(2)(H(2)O)(6)](+) cation and a Cl(−) anion. The cations in the title compound sit on a tw...

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Detalles Bibliográficos
Autores principales: Knopf, Kevin M., Crundwell, Guy, Westcott, Barry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459311/
https://www.ncbi.nlm.nih.gov/pubmed/26090164
http://dx.doi.org/10.1107/S2056989015008488
Descripción
Sumario:The crystal structure of the title compound, [YbCl(2)(H(2)O)(6)]Cl, was determined at 110 K. Samples were obtained from evaporated aceto­nitrile solutions containing the title compound, which consists of a [YbCl(2)(H(2)O)(6)](+) cation and a Cl(−) anion. The cations in the title compound sit on a twofold axis and form O—H⋯Cl hydrogen bonds with the nearby Cl(−) anion. The coordination geometry around the metal centre forms a distorted square anti­prism. The ytterbium complex is isotypic with the europium complex [Tambrornino et al. (2014 ▸). Acta Cryst. E70, i27].

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