Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride

The crystal structure of the title compound, [YbCl(2)(H(2)O)(6)]Cl, was determined at 110 K. Samples were obtained from evaporated aceto­nitrile solutions containing the title compound, which consists of a [YbCl(2)(H(2)O)(6)](+) cation and a Cl(−) anion. The cations in the title compound sit on a tw...

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Detalles Bibliográficos
Autores principales: Knopf, Kevin M., Crundwell, Guy, Westcott, Barry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459311/
https://www.ncbi.nlm.nih.gov/pubmed/26090164
http://dx.doi.org/10.1107/S2056989015008488
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author Knopf, Kevin M.
Crundwell, Guy
Westcott, Barry L.
author_facet Knopf, Kevin M.
Crundwell, Guy
Westcott, Barry L.
author_sort Knopf, Kevin M.
collection PubMed
description The crystal structure of the title compound, [YbCl(2)(H(2)O)(6)]Cl, was determined at 110 K. Samples were obtained from evaporated aceto­nitrile solutions containing the title compound, which consists of a [YbCl(2)(H(2)O)(6)](+) cation and a Cl(−) anion. The cations in the title compound sit on a twofold axis and form O—H⋯Cl hydrogen bonds with the nearby Cl(−) anion. The coordination geometry around the metal centre forms a distorted square anti­prism. The ytterbium complex is isotypic with the europium complex [Tambrornino et al. (2014 ▸). Acta Cryst. E70, i27].
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spelling pubmed-44593112015-06-18 Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride Knopf, Kevin M. Crundwell, Guy Westcott, Barry L. Acta Crystallogr E Crystallogr Commun Data Reports The crystal structure of the title compound, [YbCl(2)(H(2)O)(6)]Cl, was determined at 110 K. Samples were obtained from evaporated aceto­nitrile solutions containing the title compound, which consists of a [YbCl(2)(H(2)O)(6)](+) cation and a Cl(−) anion. The cations in the title compound sit on a twofold axis and form O—H⋯Cl hydrogen bonds with the nearby Cl(−) anion. The coordination geometry around the metal centre forms a distorted square anti­prism. The ytterbium complex is isotypic with the europium complex [Tambrornino et al. (2014 ▸). Acta Cryst. E70, i27]. International Union of Crystallography 2015-05-07 /pmc/articles/PMC4459311/ /pubmed/26090164 http://dx.doi.org/10.1107/S2056989015008488 Text en © Knopf et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Knopf, Kevin M.
Crundwell, Guy
Westcott, Barry L.
Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title_full Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title_fullStr Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title_full_unstemmed Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title_short Crystal structure of hexa­aqua­dichlorido­ytterbium(III) chloride
title_sort crystal structure of hexa­aqua­dichlorido­ytterbium(iii) chloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459311/
https://www.ncbi.nlm.nih.gov/pubmed/26090164
http://dx.doi.org/10.1107/S2056989015008488
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AT crundwellguy crystalstructureofhexaaquadichloridoytterbiumiiichloride
AT westcottbarryl crystalstructureofhexaaquadichloridoytterbiumiiichloride

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