Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate

The title compound, K(5)[H(2)PtV(9)O(28)]·9H(2)O, containing the nona­vanado­platinate(IV) polyanion, was obtained by hydro­thermal reaction at pH = 4.2. The polyanion has approximate mm2 (C (2v)) symmetry. The two platinum-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions for...

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Detalles Bibliográficos
Autores principales: Joo, Hea-Chung, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459313/
https://www.ncbi.nlm.nih.gov/pubmed/26090141
http://dx.doi.org/10.1107/S2056989015009135
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author Joo, Hea-Chung
Lee, Uk
author_facet Joo, Hea-Chung
Lee, Uk
author_sort Joo, Hea-Chung
collection PubMed
description The title compound, K(5)[H(2)PtV(9)O(28)]·9H(2)O, containing the nona­vanado­platinate(IV) polyanion, was obtained by hydro­thermal reaction at pH = 4.2. The polyanion has approximate mm2 (C (2v)) symmetry. The two platinum-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H(2)PtV(9)O(28)](2)}(10−), held together by μ(2)-O–H⋯μ(2)-O and μ(2)-O–H⋯μ(3)-O hydrogen bonds. All K(+) cations are located on general positions of the space group P-1.
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spelling pubmed-44593132015-06-18 Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate Joo, Hea-Chung Lee, Uk Acta Crystallogr E Crystallogr Commun Research Communications The title compound, K(5)[H(2)PtV(9)O(28)]·9H(2)O, containing the nona­vanado­platinate(IV) polyanion, was obtained by hydro­thermal reaction at pH = 4.2. The polyanion has approximate mm2 (C (2v)) symmetry. The two platinum-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H(2)PtV(9)O(28)](2)}(10−), held together by μ(2)-O–H⋯μ(2)-O and μ(2)-O–H⋯μ(3)-O hydrogen bonds. All K(+) cations are located on general positions of the space group P-1. International Union of Crystallography 2015-05-20 /pmc/articles/PMC4459313/ /pubmed/26090141 http://dx.doi.org/10.1107/S2056989015009135 Text en © Joo and Lee 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Joo, Hea-Chung
Lee, Uk
Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title_full Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title_fullStr Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title_full_unstemmed Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title_short Crystal structure of penta­potassium di­hydrogen nona­vanadato(V)platinate(IV) nona­hydrate
title_sort crystal structure of penta­potassium di­hydrogen nona­vanadato(v)platinate(iv) nona­hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459313/
https://www.ncbi.nlm.nih.gov/pubmed/26090141
http://dx.doi.org/10.1107/S2056989015009135
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