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Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2) N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2) N:S)(thiocyanato-κN)cadmium]
The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thiocyanate ligands and three 4-(hydroxymethyl)pyridine ligands within distorted N(4)OS octahedra. The asymmetric unit consists of one Cd(2+) cation, two thioc...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459314/ https://www.ncbi.nlm.nih.gov/pubmed/26090166 http://dx.doi.org/10.1107/S2056989015008890 |
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author | Werner, Julia Jess, Inke Näther, Christian |
author_facet | Werner, Julia Jess, Inke Näther, Christian |
author_sort | Werner, Julia |
collection | PubMed |
description | The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thiocyanate ligands and three 4-(hydroxymethyl)pyridine ligands within distorted N(4)OS octahedra. The asymmetric unit consists of one Cd(2+) cation, two thiocyanate anions and two 4-(hydroxymethyl)pyridine ligands in general positions. Two Cd(2+) cations are linked by two μ-1,3 N- and S-bonding thioycanate anions into dimers which are further linked into branched chains along [100] by two μ-1,6 N- and O-bonding 4-(hydroxymethyl)pyridine ligands. One additional N-bonded 4-(hydroxymethyl)pyridine ligand and one additional N-bonded thiocyanate anion are only terminally bonded to the metal cation. Interchain O—H⋯S hydrogen bonds between the hydroxy H atoms and one of the thiocyanate S atoms connect the chains into a three-dimensional network. |
format | Online Article Text |
id | pubmed-4459314 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44593142015-06-18 Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2) N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2) N:S)(thiocyanato-κN)cadmium] Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thiocyanate ligands and three 4-(hydroxymethyl)pyridine ligands within distorted N(4)OS octahedra. The asymmetric unit consists of one Cd(2+) cation, two thiocyanate anions and two 4-(hydroxymethyl)pyridine ligands in general positions. Two Cd(2+) cations are linked by two μ-1,3 N- and S-bonding thioycanate anions into dimers which are further linked into branched chains along [100] by two μ-1,6 N- and O-bonding 4-(hydroxymethyl)pyridine ligands. One additional N-bonded 4-(hydroxymethyl)pyridine ligand and one additional N-bonded thiocyanate anion are only terminally bonded to the metal cation. Interchain O—H⋯S hydrogen bonds between the hydroxy H atoms and one of the thiocyanate S atoms connect the chains into a three-dimensional network. International Union of Crystallography 2015-05-13 /pmc/articles/PMC4459314/ /pubmed/26090166 http://dx.doi.org/10.1107/S2056989015008890 Text en © Werner et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Werner, Julia Jess, Inke Näther, Christian Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2) N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2) N:S)(thiocyanato-κN)cadmium] |
title | Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2)
N:S)(thiocyanato-κN)cadmium] |
title_full | Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2)
N:S)(thiocyanato-κN)cadmium] |
title_fullStr | Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2)
N:S)(thiocyanato-κN)cadmium] |
title_full_unstemmed | Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2)
N:S)(thiocyanato-κN)cadmium] |
title_short | Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ(2)
N:S)(thiocyanato-κN)cadmium] |
title_sort | crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ(2)
n:o][4-(hydroxymethyl)pyridine-κn](μ-thiocyanato-κ(2)
n:s)(thiocyanato-κn)cadmium] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459314/ https://www.ncbi.nlm.nih.gov/pubmed/26090166 http://dx.doi.org/10.1107/S2056989015008890 |
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