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Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]

The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thio­cyanate ligands and three 4-(hy­droxy­meth­yl)pyridine ligands within distorted N(4)OS octa­hedra. The asymmetric unit consists of one Cd(2+) cation, two thio­c...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459314/
https://www.ncbi.nlm.nih.gov/pubmed/26090166
http://dx.doi.org/10.1107/S2056989015008890
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author Werner, Julia
Jess, Inke
Näther, Christian
author_facet Werner, Julia
Jess, Inke
Näther, Christian
author_sort Werner, Julia
collection PubMed
description The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thio­cyanate ligands and three 4-(hy­droxy­meth­yl)pyridine ligands within distorted N(4)OS octa­hedra. The asymmetric unit consists of one Cd(2+) cation, two thio­cyanate anions and two 4-(hy­droxy­meth­yl)pyridine ligands in general positions. Two Cd(2+) cations are linked by two μ-1,3 N- and S-bonding thio­ycanate anions into dimers which are further linked into branched chains along [100] by two μ-1,6 N- and O-bonding 4-(hy­droxy­meth­yl)pyridine ligands. One additional N-bonded 4-(hy­droxy­meth­yl)pyridine ligand and one additional N-bonded thio­cyanate anion are only terminally bonded to the metal cation. Inter­chain O—H⋯S hydrogen bonds between the hy­droxy H atoms and one of the thio­cyanate S atoms connect the chains into a three-dimensional network.
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spelling pubmed-44593142015-06-18 Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium] Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports The crystal structure of the title compound, [Cd(NCS)(2)(C(6)H(7)NO)(2)](n) is made up of Cd(2+) cations that are coordinated by three thio­cyanate ligands and three 4-(hy­droxy­meth­yl)pyridine ligands within distorted N(4)OS octa­hedra. The asymmetric unit consists of one Cd(2+) cation, two thio­cyanate anions and two 4-(hy­droxy­meth­yl)pyridine ligands in general positions. Two Cd(2+) cations are linked by two μ-1,3 N- and S-bonding thio­ycanate anions into dimers which are further linked into branched chains along [100] by two μ-1,6 N- and O-bonding 4-(hy­droxy­meth­yl)pyridine ligands. One additional N-bonded 4-(hy­droxy­meth­yl)pyridine ligand and one additional N-bonded thio­cyanate anion are only terminally bonded to the metal cation. Inter­chain O—H⋯S hydrogen bonds between the hy­droxy H atoms and one of the thio­cyanate S atoms connect the chains into a three-dimensional network. International Union of Crystallography 2015-05-13 /pmc/articles/PMC4459314/ /pubmed/26090166 http://dx.doi.org/10.1107/S2056989015008890 Text en © Werner et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Werner, Julia
Jess, Inke
Näther, Christian
Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title_full Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title_fullStr Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title_full_unstemmed Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title_short Crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) N:O][4-(hy­droxy­meth­yl)pyridine-κN](μ-thio­cyanato-κ(2) N:S)(thio­cyanato-κN)cadmium]
title_sort crystal structure of poly[[μ-4-(hy­droxy­meth­yl)pyridine-κ(2) n:o][4-(hy­droxy­meth­yl)pyridine-κn](μ-thio­cyanato-κ(2) n:s)(thio­cyanato-κn)cadmium]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459314/
https://www.ncbi.nlm.nih.gov/pubmed/26090166
http://dx.doi.org/10.1107/S2056989015008890
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