Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride

In the title mol­ecular salt, C(10)H(15)ClNS(+)·Cl(−), the cation is [R′R"NH(2)](+), where R′ is 2-MeS-C(6)H(4)CH(2)– and R" is –CH(2)CH(2)Cl, and the anion is Cl(−). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra­hedral geometry. In the crystal, the ani...

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Autores principales: Raghavendra Kumar, P., Shailesh, Upereti, Palakshamurthy, B. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459316/
https://www.ncbi.nlm.nih.gov/pubmed/26090135
http://dx.doi.org/10.1107/S2056989015008221
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author Raghavendra Kumar, P.
Shailesh, Upereti
Palakshamurthy, B. S.
author_facet Raghavendra Kumar, P.
Shailesh, Upereti
Palakshamurthy, B. S.
author_sort Raghavendra Kumar, P.
collection PubMed
description In the title mol­ecular salt, C(10)H(15)ClNS(+)·Cl(−), the cation is [R′R"NH(2)](+), where R′ is 2-MeS-C(6)H(4)CH(2)– and R" is –CH(2)CH(2)Cl, and the anion is Cl(−). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra­hedral geometry. In the crystal, the anions are connected to the cations through two pairs of N—H⋯Cl hydrogen bonds, generating a four-centred inversion dimer with an R (4) (2)(8) ring motif.
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spelling pubmed-44593162015-06-18 Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride Raghavendra Kumar, P. Shailesh, Upereti Palakshamurthy, B. S. Acta Crystallogr E Crystallogr Commun Research Communications In the title mol­ecular salt, C(10)H(15)ClNS(+)·Cl(−), the cation is [R′R"NH(2)](+), where R′ is 2-MeS-C(6)H(4)CH(2)– and R" is –CH(2)CH(2)Cl, and the anion is Cl(−). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra­hedral geometry. In the crystal, the anions are connected to the cations through two pairs of N—H⋯Cl hydrogen bonds, generating a four-centred inversion dimer with an R (4) (2)(8) ring motif. International Union of Crystallography 2015-05-13 /pmc/articles/PMC4459316/ /pubmed/26090135 http://dx.doi.org/10.1107/S2056989015008221 Text en © Raghavendra Kumar et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Raghavendra Kumar, P.
Shailesh, Upereti
Palakshamurthy, B. S.
Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title_full Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title_fullStr Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title_full_unstemmed Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title_short Crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
title_sort crystal structure of (2-chloro­eth­yl)[2-(methyl­sulfan­yl)benz­yl]ammonium chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459316/
https://www.ncbi.nlm.nih.gov/pubmed/26090135
http://dx.doi.org/10.1107/S2056989015008221
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