Crystal structure of bis­[μ-bis­(di­phenyl­phosphan­yl)methane-κ(2) P:P′]-μ-chlorido-chlorido-1κCl-(1-phenyl­thio­urea-2κS)disilver aceto­nitrile hemisolvate

In the dinuclear title complex, [Ag(2)Cl(2)(C(7)H(8)N(2)S)(C(25)H(22)P(2))(2)]·0.5CH(3)CN, each Ag(I) ion displays a distorted tetra­hedral coordination geometry with two P atoms from two bis­(di­phenyl­phosphan­yl)methane (dppm) ligands, one bridging chloride ion, one terminal chloride ion and one terminal S atom from the N,N′-phenyl­thio­urea (ptu) ligand. The dppm ligands and the bridging chloride ion force the two Ag atoms into close proximity, with a short Ag⋯Ag separation of 3.2064 (2) Å. In the crystal, complex mol­ecules are linked by N—H⋯Cl hydrogen bonds forming a dimer. The dimers are linked via weak C— H⋯Cl hydrogen bonds forming a two-dimensional supra­molecular architecture in the yz plane. In addition, an intra­molecular N—H⋯Cl hydrogen bond is observed.